三丁基(1-乙氧基乙烯)锡结构式
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常用名 | 三丁基(1-乙氧基乙烯)锡 | 英文名 | Tributyl(1-ethoxyvinyl)stannane |
|---|---|---|---|---|
| CAS号 | 97674-02-7 | 分子量 | 361.151 | |
| 密度 | 1.069 | 沸点 | 319.2±0.0 °C at 760 mmHg | |
| 分子式 | C16H34OSn | 熔点 | <0ºC | |
| MSDS | 中文版 美版 | 闪点 | 160.3±28.4 °C | |
| 符号 |
GHS06, GHS08, GHS09 |
信号词 | Danger |
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A new route for installing the isocyclic ring on chlorins yielding 13 1-oxophorbines.
J. Org. Chem. 71 , 7049, (2006) A new route to 13(1)-oxophorbines, the parent macrocycle of chlorophylls, begins with the synthesis of a 13-bromochlorin. Pd-mediated coupling of the latter with tributyl(1-ethoxyvinyl)tin and subsequent acidic hydrolysis afforded the 13-acetylchlorin (1). Tr... |
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Intramolecular Photocycloaddition of Unsaturated Isoquinuclidines. Synthesis of 2-Azatetracyclo[4.0.0.(4,9)0(7,10)]decanes and 3-Azatetracyclo[6.1.1.0.(2,7)0(5,9)]decanes.
J. Org. Chem. 69 , 3758-3764, (2004) 2-Azabicyclo[2.2.2]oct-5-enes bearing an endo alkenyl substituent were synthesized by Diels-Alder addition of methyl vinyl ketone to a 1,6-dihydropyridine derived from methyl nicotinate. Although 1,5-dienes with this skeleton were unreactive under thermal con... |
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