偶氮二甲酸二叔丁酯结构式
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常用名 | 偶氮二甲酸二叔丁酯 | 英文名 | Di-tert-Butyl azodicarboxylate |
|---|---|---|---|---|
| CAS号 | 870-50-8 | 分子量 | 230.261 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 287.1±9.0 °C at 760 mmHg | |
| 分子式 | C10H18N2O4 | 熔点 | 89-92 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 107.2±13.2 °C | |
| 符号 |
GHS08 |
信号词 | Danger |
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Axially chiral guanidine as highly active and enantioselective catalyst for electrophilic amination of unsymmetrically substituted 1,3-dicarbonyl compounds.
J. Am. Chem. Soc. 128 , 16044, (2006) A newly designed axially chiral guanidine is found to function as an effective platform for asymmetric induction at the alpha-carbon of unsymmetrically substituted 1,3-dicarbonyl compounds. Highly efficient and enantioselective electrophilic amination of vari... |
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Chirally aminated 2-naphthols--organocatalytic synthesis of non-biaryl atropisomers by asymmetric Friedel-Crafts amination.
Angew. Chem. Int. Ed. Engl. 45(7) , 1147-1151, (2006)
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Catalytic Enantioselective Reaction of α-Aminoacetonitriles Using Chiral Bis(imidazoline) Palladium Catalysts.
Angew. Chem. Int. Ed. Engl. 54(28) , 8198-202, (2015) The catalytic enantioselective reaction of diphenylmethylidene-protected α-aminoacetonitriles with imines has been developed. Good yields and diastereo- and enantioselectivities were observed for the reaction of various imines using chiral bis(imidazoline)/Pd... |
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Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD.
Org. Biomol. Chem. 10(6) , 1158-61, (2012) We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for... |
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