五氟苯酚
五氟苯酚结构式
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常用名 | 五氟苯酚 | 英文名 | Pentafluorophenol |
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| CAS号 | 771-61-9 | 分子量 | 184.06 | |
| 密度 | 1.7±0.1 g/cm3 | 沸点 | 146.3±35.0 °C at 760 mmHg | |
| 分子式 | C6HF5O | 熔点 | 34-36 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 72.2±0.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Total synthesis and confirmation of the revised structures of azaspiracid-2 and azaspiracid-3.
Angew. Chem. Int. Ed. Engl. 45(16) , 2609-15, (2006)
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Atmospheric pressure chemical ionization of fluorinated phenols in atmospheric pressure chemical ionization mass spectrometry, tandem mass spectrometry, and ion mobility spectrometry.
J. Am. Soc. Mass Spectrom. 10(11) , 1157-65, (1999) Atmospheric pressure chemical ionization (APCI)-mass spectrometry (MS) for fluorinated phenols (C6H5-xFxOH Where x = 0-5) in nitrogen with Cl- as the reagent ion yielded product ions of M Cl- through ion associations or (M-H)- through proton abstractions. Pro... |
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Development and validation of a RP-HPLC method for the determination of gentamicin sulfate and its related substances in a pharmaceutical cream using a short pentafluorophenyl column and a charged aerosol detector.
J. Pharm. Biomed. Anal. 51(3) , 521-31, (2010) Gentamicin sulfate is a potent broad spectrum aminoglycoside antibiotic which is used as an active pharmaceutical ingredient (API) against both Gram-positive and Gram-negative bacteria. A reversed-phase high performance liquid chromatographic (RP-HPLC) method... |
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Carbonic anhydrase inhibitors: X-ray crystal structure of a benzenesulfonamide strong CA II and CA IX inhibitor bearing a pentafluorophenylaminothioureido tail in complex with isozyme II.
Bioorg. Med. Chem. Lett. 15(7) , 1937-42, (2005) N-1-(4-Sulfamoylphenyl)-N-4-pentafluorophenyl-thiosemicarbazide was prepared by the reaction of 4-isothiocyanato-benzenesulfonamide with pentafluorophenyl hydrazine, and proved to be an effective inhibitor of several isozymes of the zinc enzyme carbonic anhyd... |
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Trichlorophenol (TCP) sulfonate esters: a selective alternative to pentafluorophenol (PFP) esters and sulfonyl chlorides for the preparation of sulfonamides.
Chem. Commun. (Camb.) (10) , 1074-6, (2007) 2,4,6-Trichlorophenol (TCP) sulfonate esters undergo effective aminolysis under conventional heating and microwave irradiation; the reactivity of these species is such that chemoselective transformations of PFP sulfonate esters can be achieved. |
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Pentafluorophenyl copper: aggregation and complexation phenomena, photoluminescence properties, and applications as reagent in organometallic synthesis.
Dalton Trans. (27) , 2851-8, (2007) Recent advances in the chemistry of pentafluorophenyl copper are discussed, including the observation of strongly luminescent adducts with pyridine, the first successful structural characterization of an organocopper-arene complex, and the complexation with e... |
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Liquid chromatography-electrospray ionization-mass spectrometric quantitation of juvenile hormone III in whole body extracts of the Formosan subterranean termite.
J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 877(27) , 3175-80, (2009) Juvenile hormone (JH) III is responsible for control of a variety of insect physiological and developmental states, including caste differentiation of the Formosan subterranean termite (Coptotermes formosanus Shiraki). We report here a simplified, efficient s... |
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Oxidative dehalogenation of perhalogenated benzenes by cytochrome P450 compound I.
Biochemistry 46(20) , 5924-40, (2007) Resolution of the identity PBE (RI-PBE) and B3LYP density functional theory calculations are used to understand the cytochrome P450-catalyzed, Compound I-mediated oxidation of perchlorobenzenes, perfluorobenzenes, their phenols, and mixed chlorofluorobenzenes... |
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Analysis of the association of cobalt(III) chelates with fluorine-containing phenols in supercritical carbon dioxide.
Talanta 146 , 789-94, (2015) The solubilities of several cobalt(III) chelates (CoL3) with in supercritical carbon dioxide (SC-CO2) were investigated in the presence of fluorine- and trifluoromethyl-substituted phenols (PhOH) using UV-vis spectrophotometry. Solubility enhancement of CoL3 ... |
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The pharmacokinetics of anthocyanins and their metabolites in humans.
Br. J. Pharmacol. 171(13) , 3268-82, (2014) Anthocyanins are phytochemicals with reported vasoactive bioactivity. However, given their instability at neutral pH, they are presumed to undergo significant degradation and subsequent biotransformation. The aim of the present study was to establish the phar... |