芦竹碱

芦竹碱结构式
芦竹碱结构式
品牌特惠专场
常用名 芦竹碱 英文名 Gramine
CAS号 87-52-5 分子量 174.242
密度 1.1±0.1 g/cm3 沸点 293.9±15.0 °C at 760 mmHg
分子式 C11H14N2 熔点 132-134 °C(lit.)
MSDS 中文版 美版 闪点 131.5±20.4 °C

A retro-biosynthetic approach to the prediction of biosynthetic pathways from position-specific isotope analysis as shown for tramadol.

Proc. Natl. Acad. Sci. U. S. A. 112 , 8296-301, (2015)

Tramadol, previously only known as a synthetic analgesic, has now been found in the bark and wood of roots of the African medicinal tree Nauclea latifolia. At present, no direct evidence is available as to the biosynthetic pathway of its unusual skeleton. To ...

NMR-titrations with complexes between ds-DNA and indole derivatives including tryptophane containing peptides.

FEBS Lett. 374(3) , 387-92, (1995)

It is shown that NMR titrations can be used on a quantitative basis to derive binding constants and binding modes of ds-DNA ligand complexes from several signals. The results are partially at variance with literature conclusions; they can be interpreted by ad...

Response of animals to dietary gramine. I. Performance and selected hematological, biochemical and histological parameters in growing chicken, rats and pigs.

Arch. Tierernahr. 55(1) , 1-16, (2001)

The effects of feeding varied levels of low- and high-gramine yellow lupin seeds (LG and HG, respectively), and of synthetic gramine added to the diets in amounts ranging from 0.15 to 1.2 g per kg were investigated in one experiment on growing chicken and in ...

Gramine increase associated with rapid and transient systemic resistance in barley seedlings induced by mechanical and biological stresses.

Plant Cell Physiol. 42(10) , 1103-11, (2001)

Systemic acquired resistance (SAR) is one of the intriguing issues for studying the mechanism in signal transduction system in a whole plant. We found that SAR and increase of an antifungal compound were induced rapidly and transiently in barley (Hordeum vulg...

Alkaloid-fullerene systems through photocycloaddition reactions.

J. Org. Chem. 65(12) , 3804-10, (2000)

The photocycloaddition of tertiary amines to ¿60fullerene (C(60)) is an interesting and useful reaction. We wished to extend the applications of this type of reaction through an investigation of the photoaddition of alkaloids to C(60) for the purpose of synth...

Detoxification of gramine by the cereal aphid Sitobion avenae.

J. Chem. Ecol. 35(3) , 320-5, (2009)

Secondary metabolites play an important role in host plant resistance to insects, and insects, in turn, may develop mechanisms to counter plant resistance mechanisms. In this study, we investigated the toxicity of gramine to the cereal aphid Sitobion avenae a...

N-Methyltransferase involved in gramine biosynthesis in barley: cloning and characterization.

Phytochemistry 67(18) , 2002-8, (2006)

The indole alkaloid gramine occurs in leaves of certain barley (Hordeum vulgare L.) cultivars but not in others. A gene sequence in barley that earlier was characterized as a jasmonate-induced O-methyltransferase (MT) (EC 2.1.1.6, GenBank accession U54767) wa...

Response of animals to dietary gramine. II. Effects of feeding high-gramine yellow lupin seeds on reproductive performance of rats and on selected hematological and biochemical parameters in offspring.

Arch. Tierernahr. 55(1) , 17-24, (2001)

Two groups of 26 male and 26 female rats at the initial age 30 +/- 2 days were fed during 31 weeks on diets containing 20 percent of yellow lupin seeds having low (LG) or high (HG) gramine content. The animals were mated twice within nutritional groups, 1 mal...

Gramine: a vasorelaxing alkaloid acting on 5-HT(2A) receptors.

Planta Med. 70(4) , 373-5, (2004)

The vascular effects of gramine on resistance vessels were evaluated, in particular as regards the 5-hydroxytryptamine (5-HT) system. We compared the action of gramine with that of ketanserin, a 5-HT (2A) antagonist; both compounds induced concentration-depen...

Differential regulation of 3-aminomethylindole/N-methyl-3-aminomethylindole N-methyltransferase and gramine in barley by both biotic and abiotic stress conditions.

Plant Physiol. Biochem. 49(1) , 96-102, (2011)

The expression of NMT (3-aminomethylindole/N-methyl-3-aminomethylindole N-methyltransferase; EC 2.1.1.), involved in the biosynthesis of the indole alkaloid gramine, was investigated in aphid-infested barley (Hordeum vulgare L.). NMT is induced by methyl jasm...