内消旋-1,2-二苯基乙二胺结构式
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常用名 | 内消旋-1,2-二苯基乙二胺 | 英文名 | meso-1,2-Diphenylethylenediamine |
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| CAS号 | 951-87-1 | 分子量 | 212.29000 | |
| 密度 | 1.106g/cm3 | 沸点 | 353.9ºC at 760mmHg | |
| 分子式 | C14H16N2 | 熔点 | 118-122ºC | |
| MSDS | 中文版 美版 | 闪点 | 199.9ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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Synthesis and characterisation of nickel Schiff base complexes containing the meso-1,2-diphenylethylenediamine moiety: selective interactions with a tetramolecular DNA quadruplex.
Dalton Trans. 44(7) , 3136-50, (2015) As part of a program of preparing metal complexes which exhibit unique affinities towards different DNA structures, we have synthesised the novel Schiff base complex N,N'-bis-4-(hydroxysalicylidine)meso-diphenylethylenediaminenickel(ii) (), via the reaction o... |
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Enantioseparation of 1-arylethanols via a supramolecular chiral host consisting of N-(2-naphthoyl)-L-aspartic acid and an achiral diamine.
Org. Biomol. Chem. 10(9) , 1877-82, (2012) A supramolecular chiral host consisting of N-(2-naphthoyl)-L-aspartic acid (L-1) and meso-1,2-diphenylethylenediamine (2) is effective in enantioseparation of 1-arylethanols (up to 96% ee with 100% inclusion ratio). Here we report three different methods to p... |
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Synthesis and antiviral activities of N-mono- and/or N,N'-di-carbamoyl and acyl derivatives of symmetrical diamines.
Chem. Pharm. Bull. 56(7) , 1052-8, (2008) N-carbamoyl and N-acyl diamine derivatives were synthesized from symmetrical diamines by their addition to iso(thio)cyanates, cleavage reaction of acid anhydride, or N-acylation by acyl chloride. (1R,2R)-1,2-Diaminocyclohexane [(1R,2R)-1], meso-1,2-diaminocyc... |
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Stereoselective Synthesis of (1R, 2S, 3R)-Camphordiamine. Busacca CA, et al.
J. Org. Chem. 65(15) , 4753-55, (2000)
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In silico fragment-based discovery of DPP-IV S1 pocket binders.
Bioorg. Med. Chem. Lett. 16 , 1405-9, (2006) Dipeptidyl peptidase IV is a clinically validated target for type-2 diabetes and belongs to a family of peptidases with a quite unique post-proline cleavage specificity. Known inhibitors contain a limited number of molecular anchors occupying the small protot... |
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Analysis of leucine enkephalin by high-performance liquid chromatography using enzymatic derivatization by tyrosinase and electrochemical or fluorescence detection.
J. Pharm. Biomed. Anal. 19(6) , 855-64, (1999) Two tyrosine specific, HPLC methods with either electrochemical (HPLC-ED) or fluorescence (HPLC-FL) detection are described for leucine-enkephalin (LE) in cerebrospinal fluid (CSF). Both approaches involve the hydroxylation of the Tyr1-moiety of LE by mushroo... |
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A new fluorogenic assay for tyrosine-containing peptides.
J. Pharm. Biomed. Anal. 9(7) , 557-63, (1991) A new tyrosine-specific LC assay with pre-column fluorogenic derivatization is described for Tyr-Gly as model peptide. o-Hydroxylation of the tyrosine residue with tyrosinase in the presence of ascorbic acid, followed by oxidation to the corresponding quinone... |
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Diphenylethanediamine (DPEDA) as chiral selector: VII. Efficient HPLC resolution of a series of underivatized diarylcarbinols on a chiral stationary phase based on C5-amide-bonded N-3,5-dinitrobenzyl-DPEDA.
Chirality 8(7) , 490-93, (1996) Fast and efficient baseline separation of asymmetrically substituted diarylmethanols and 1,1-diarylethanols was achieved on an endcapped, amide-linked N-3,5-dinitrobenzoylated, (R,R)-1,2-diphenyl-1,2-ethanediamine-derived chiral stationary phase (CSP). Optima... |