磺酰氯
一般危化品
磺酰氯结构式
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常用名 | 磺酰氯 | 英文名 | Sulfuryl chloride |
|---|---|---|---|---|
| CAS号 | 7791-25-5 | 分子量 | 134.970 | |
| 密度 | 1.667 | 沸点 | 69 ºC | |
| 分子式 | Cl2O2S | 熔点 | -54.1 °C | |
| MSDS | 中文版 美版 | 闪点 | 69.1°C | |
| 符号 |
GHS05, GHS07 |
信号词 | Danger |
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Trichlorophenol (TCP) sulfonate esters: a selective alternative to pentafluorophenol (PFP) esters and sulfonyl chlorides for the preparation of sulfonamides.
Chem. Commun. (Camb.) (10) , 1074-6, (2007) 2,4,6-Trichlorophenol (TCP) sulfonate esters undergo effective aminolysis under conventional heating and microwave irradiation; the reactivity of these species is such that chemoselective transformations of PFP sulfonate esters can be achieved. |
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Detection of Infertility-related Neutralizing Antibodies with a Cell-free Microfluidic Method.
Sci. Rep. 5 , 16551, (2015) The unwanted emergence of neutralizing antibodies (nAbs) against an endogenous or a therapeutic protein can result in deficiency diseases or therapy failure. Here, we developed a cell-free microfluidic method for the sensitive detection and quantification of ... |
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pH-activated nanoparticles for controlled topical delivery of farnesol to disrupt oral biofilm virulence.
ACS Nano 9(3) , 2390-404, (2015) Development of effective therapies to control oral biofilms is challenging, as topically introduced agents must avoid rapid clearance from biofilm-tooth interfaces while targeting biofilm microenvironments. Additionally, exopolysaccharides-matrix and acidific... |
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Early endosomal escape of a cyclic cell-penetrating peptide allows effective cytosolic cargo delivery.
Biochemistry 53(24) , 4034-46, (2014) Cyclic heptapeptide cyclo(FΦRRRRQ) (cFΦR4, where Φ is l-2-naphthylalanine) was recently found to be efficiently internalized by mammalian cells. In this study, its mechanism of internalization was investigated by perturbing various endocytic events through th... |
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Detection and quantitation of succinimide in intact protein via hydrazine trapping and chemical derivatization.
J. Pharm. Sci. 103(10) , 3033-42, (2014) The formation of aspartyl succinimide is a common post-translational modification of protein pharmaceuticals under acidic conditions. We present a method to detect and quantitate succinimide in intact protein via hydrazine trapping and chemical derivatization... |
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Catalytic asymmetric formation of beta-sultams.
Org. Lett. 9 , 2007, (2007) beta-Sultams, highly strained sulfonyl analogues of beta-lactams, were prepared enantio- and diastereoselectively by tertiary amine catalyzed [2 + 2] cycloaddition reactions. The title compounds are practical precursors of highly enantioenriched biologically ... |
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Estimation of enantiomeric impurity in piperidin-3-amine by chiral HPLC with precolumn derivatization.
Chirality , doi:10.1002/chir.22352, (2014) A simple, precise, accurate, robust chiral high-performance liquid chromatographic (chiral HPLC) method was developed for estimation of (S)-piperidin-3-amine (S-isomer) in (R)-piperidin-3-amine dihydrochloride (R-AMP). As AMP is a high-melting solid and nonch... |
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Ruthenium-catalyzed meta sulfonation of 2-phenylpyridines.
J. Am. Chem. Soc. 133(48) , 19298-301, (2011) A selective catalytic meta sulfonation of 2-phenylpyridines was found to occur in the presence of (arene)ruthenium(II) complexes upon reaction with sulfonyl chlorides. The 2-pyridyl group facilitates the formation of a stable Ru-C(aryl) σ bond that induces a ... |
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Molecular structure, vibrational spectroscopic, first hyperpolarizability, NBO and HOMO, LUMO studies of P-Iodobenzene sulfonyl chloride.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 82(1) , 332-9, (2011) In this work, the experimental and theoretical vibrational spectra of P-Iodobenzene sulfonyl chloride (P-IBSC) were studied. P-IBSC and its derivatives present in many biologically active compounds. Because of their spectroscopic properties and chemical signi... |
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A convenient enantioselective synthesis of (S)-alpha-trifluoromethylisoserine.
J. Org. Chem. 70(14) , 5721-4, (2005) [reaction: see text] This report describes two straightforward synthetic methodologies to obtain alpha-CF3-isoserine, a new alpha,alpha-disubstituted beta-amino acid, from alpha-(trifluoromethyl)acrylic acid. The routes involve the synthesis of five-membered ... |