2-噻吩硼酸
2-噻吩硼酸结构式
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常用名 | 2-噻吩硼酸 | 英文名 | Thienylboronic acid |
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| CAS号 | 6165-68-0 | 分子量 | 127.957 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 287.9±32.0 °C at 760 mmHg | |
| 分子式 | C4H5BO2S | 熔点 | 138-140 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 127.9±25.1 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Geometry relaxation-induced large Stokes shift in red-emitting borondipyrromethenes (BODIPY) and applications in fluorescent thiol probes.
J. Org. Chem. 5th ed., 77 , 2192-2206, (2012) 2-Thienyl and 2,6-bisthienyl BODIPY derivatives (BS-SS and BS-DS) were prepared that show intense absorption (ε = 65000 M(-1) cm(-1) at 507 nm) and a large Stokes shift (96 nm) vs the small Stokes shift of typical BODIPY (<15 nm). Control compounds with a thi... |
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Design of potent and selective hybrid inhibitors of the mitotic kinase Nek2: structure-activity relationship, structural biology, and cellular activity.
J. Med. Chem. 7th ed., 55 , 3228-3241, (2012) We report herein a series of Nek2 inhibitors based on an aminopyridine scaffold. These compounds have been designed by combining key elements of two previously discovered chemical series. Structure based design led to aminopyridine (R)-21, a potent and select... |
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Fullerenyl boronic esters: ferric perchlorate-mediated synthesis and functionalization.
Org. Lett. 7th ed., 14 , 1800-1803, (2012) Fullerenyl boronic esters have been prepared by a ferric perchlorate-promoted reaction of [60]fullerene with various arylboronic acids. The obtained fullerenyl boronic esters could undergo further functionalization with diols to afford C(60)-fused dioxane/dio... |
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Ligand effects on the stereochemical outcome of Suzuki-Miyaura couplings.
J. Org. Chem. 8th ed., 77 , 3700-3703, (2012) The ligands associated with various Pd catalysts play a crucial role in determining the stereochemistry of cross-couplings between boronic acids and Z-alkenyl halides. A ligand on palladium has been found that leads to the desired products under mild conditio... |
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Polycyclic aromatic triptycenes: oxygen substitution cyclization strategies.
J. Am. Chem. Soc. 17th ed., 134 , 7282-7285, (2012) The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold enforces proximity of the alcohol and aren... |
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A fluorescein-labeled AmpC β-lactamase allows rapid characterization of β-lactamase inhibitors by real-time fluorescence monitoring of the β-lactamase-inhibitor interactions.
Biotechnol. J. 11 , 257-65, (2016) Rapid emergence of class C β-lactamases has urged an immediate need for developing class C β-lactamase specific inhibitors for effective clinical treatment. To facilitate the development of effective class C β-lactamase inhibitors, we propose a new approach f... |
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Copper-catalyzed nitration of arylboronic acids with nitrite salts under mild conditions: an efficient synthesis of nitroaromatics Yan, G.; Zhang, L.; Yu, J.
Lett. Org. Chem. 2nd ed., 9 , 133-137, (2012)
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Carbon-Carbon Bond Formation by Ligand-free Cross-Coupling Reaction Using Palladium Catalyst Supported on Synthetic Adsorbent Monguchi, Y.; et al.
ChemCatChem 4th ed., 4 , 546-558, (2012)
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Synthesis of a novel fluorene derivative for polyfluorenes. 7,7'-Di(5-bromothiophen-2-yl)-9,9,9',9'-tetraoctyl-2,2'-bifluorene Li, L.; et al.
Adv. Mater. Res. , 418-420, (2012)
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Chain-growth catalyst transfer polycondensation of a conjugated alternating copolymer Ono, R. J.; Bielawski, C. W.
Polym. Mat. Sci. Eng. Preprints , (2012)
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