2-甲基咪唑
2-甲基咪唑结构式
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常用名 | 2-甲基咪唑 | 英文名 | 2-Methylimidazole |
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| CAS号 | 693-98-1 | 分子量 | 82.104 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 267-268 ºC | |
| 分子式 | C4H6N2 | 熔点 | 142-145 ºC | |
| MSDS | 中文版 美版 | 闪点 | 155 ºC | |
| 符号 |
GHS05, GHS07, GHS08 |
信号词 | Danger |
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Development of a novel magnetic molecularly imprinted polymer coating using porous zeolite imidazolate framework-8 coated magnetic iron oxide as carrier for automated solid phase microextraction of estrogens in fish and pork samples.
J. Chromatogr. A. 1365 , 35-44, (2014) A high-performance magnetic molecularly imprinted polymer (MIP) coating using zeolite imidazolate framework-8 coated magnetic iron oxide (Fe3O4@ZIF-8) as a carrier was developed for simultaneous automated solid phase microextraction of four estrogens in 24 fo... |
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A new strategy to determine the protein mutation site using matrix-assisted laser desorption ionization in-source decay: derivatization by ionic liquid.
Anal. Chim. Acta 865 , 31-8, (2015) Matrix-assisted laser desorption ionization (MALDI) time-of-flight mass spectrometry (TOF-MS) can be considered as state of the art in the field of proteins and peptides analysis. In this work, we have designed an ionic liquid derivative strategy to obtain ab... |
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Design of Zeolitic Imidazolate Framework Derived Nitrogen-Doped Nanoporous Carbons Containing Metal Species for Carbon Dioxide Fixation Reactions.
ChemSusChem 8 , 3905-12, (2015) Various N-doped nanoporous carbons containing metal species were prepared by direct thermal conversion of zeolitic imidazolate frameworks (ZIFs; ZIF-7, -8, -9, and -67) at different temperatures (600, 800, and 1000 °C). These materials were utilized as bifunc... |
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Comparative chemometric modeling of cytochrome 3A4 inhibitory activity of structurally diverse compounds using stepwise MLR, FA-MLR, PLS, GFA, G/PLS and ANN techniques.
Eur. J. Med. Chem. 44 , 2913-22, (2009) Twenty-eight structurally diverse cytochrome 3A4 (CYP3A4) inhibitors have been subjected to quantitative structure-activity relationship (QSAR) studies. The analyses were performed with electronic, spatial, topological, and thermodynamic descriptors calculate... |
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High-performance Polymer Membranes with Multi-functional Amphiphilic Micelles for CO2 Capture.
ChemSusChem 8 , 3783-92, (2015) Herein, we report a high performance polymer membrane with simultaneously large improvements in the CO2 permeability and CO2/N2 selectivity. These improvements are obtained by incorporation of a multi-functional amphiphilic comb copolymer micelle, that is, po... |
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Asymmetric Supercapacitors Using 3D Nanoporous Carbon and Cobalt Oxide Electrodes Synthesized from a Single Metal-Organic Framework.
ACS Nano 9 , 6288-96, (2015) Nanoporous carbon and nanoporous cobalt oxide (Co3O4) materials have been selectively prepared from a single metal-organic framework (MOF) (zeolitic imidazolate framework, ZIF-67) by optimizing the annealing conditions. The resulting ZIF-derived carbon posses... |
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Metal oxide-coated three-dimensional graphene prepared by the use of metal-organic frameworks as precursors.
Angew. Chem. Int. Ed. Engl. 53(5) , 1404-9, (2014) A simple method for the preparation of metal-oxide-coated three-dimensional (3D) graphene composites was developed. The metal-organic frameworks (MOFs) that served as the precursors of the metal oxides were first synthesized on the 3D graphene networks (3DGNs... |
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Significantly Enhanced Separation using ZIF-8 Membranes by Partial Conversion of Calcined Layered Double Hydroxide Precursors.
ChemSusChem 8 , 3582-6, (2015) Significantly enhanced H2 /CH4 (ca. 80) selectivity was realized by effective suppression of the framework flexibility of a prepared ZIF-8 membrane. Initially a ZnO buffer layer consisting of 20 nm-sized ZnO-nanoparticle aggregates was fabricated by controlle... |
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Fabrication of fluorescent SiO2@zeolitic imidazolate framework-8 nanosensor for Cu(2+) detection.
Analyst 140(2) , 623-9, (2014) A simple strategy to fabricate a fluorescent SiO2@zeolitic imidazolate framework-8 (ZIF-8) core-shell nanosensor for Cu(2+) detection was demonstrated in this work. The nanosensor was synthesized using carboxyl-functionalized SiO2 nanoparticles (SiO2 NPs) as ... |
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Copper-catalyzed N-arylation of imidazoles and benzimidazoles.
J. Org. Chem. 72 , 6190, (2007) 4,7-Dimethoxy-1,10-phenanthroline (L1c) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazoles and benzimidazoles with both aryl iodides and bromides under mild conditions. Further optimization of the system has revealed that t... |