富马酰氯
一般危化品
富马酰氯结构式
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常用名 | 富马酰氯 | 英文名 | Fumaryl chloride |
|---|---|---|---|---|
| CAS号 | 627-63-4 | 分子量 | 152.96300 | |
| 密度 | 1.415 g/mL at 25 °C(lit.) | 沸点 | 161-164 °C(lit.) | |
| 分子式 | C4H2Cl2O2 | 熔点 | -2 °C | |
| MSDS | 中文版 美版 | 闪点 | 165 °F | |
| 符号 |
GHS05, GHS07 |
信号词 | Danger |
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Synthesis of poly(propylene fumarate) by acylation of propylene glycol in the presence of a proton scavenger.
J. Biomater. Sci. Polym. Ed. 10(3) , 363-73, (1999) To synthesize high molecular weight poly(propylene fumarate) (PPF), fumaryl chloride and propylene glycol were reacted in the presence of potassium carbonate, which serves as a proton scavenger. Transesterification of the resulting low molecular weight oligom... |
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Dynamics of Cl (2Pj) atom formation in the photodissociation of fumaryl chloride (ClCO - CH = CH - COCl) at 235 nm: a resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) study.
J. Phys. Chem. A 115(9) , 1538-46, (2011) The photodissociation dynamics of fumaryl chloride (ClCO-CH═CH-COCl) has been studied in a supersonic molecular beam around 235 nm using resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) technique by detecting the nascent state of the pri... |
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Synthesis of oligo(poly(ethylene glycol) fumarate).
Nat. Protoc. 7(6) , 1219-27, (2012) This protocol describes the synthesis of oligo(poly(ethylene glycol) fumarate) (OPF; 1-35 kDa; a polymer useful for tissue engineering applications) by a one-pot reaction of poly(ethylene glycol) (PEG) and fumaryl chloride. The procedure involves three parts:... |
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Modification of oligo(poly(ethylene glycol) fumarate) macromer with a GRGD peptide for the preparation of functionalized polymer networks.
Biomacromolecules 2(1) , 255-61, (2001) A novel macromer, oligo(poly(ethylene glycol) fumarate) (OPF), was synthesized by the reaction between poly(ethylene glycol) (PEG) of molecular weight 1000 (PEG 1.0K) and fumaryl chloride. The oligo(PEG fumarate) (OPF 1.0K) was modified with a peptide known t... |
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UV-laser photoisomerization of fumaryl chloride: the first identification of maleoyl chloride: matrix isolation infrared and ab initio studies.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 56A(1) , 157-65, (2000) Fourier transform infrared spectra of fumaryl chloride 1 isolated in an argon matrix at 10 K have been analyzed. The comparison between the ab initio HF/6-31G calculated infrared spectra with the experimental ones reveals the existence of three planar conform... |