2-氟乙醇
2-氟乙醇结构式
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常用名 | 2-氟乙醇 | 英文名 | 2-Fluoroethanol |
|---|---|---|---|---|
| CAS号 | 371-62-0 | 分子量 | 64.059 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 103.5±0.0 °C at 760 mmHg | |
| 分子式 | C2H5FO | 熔点 | −26.5 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 31.1±0.0 °C | |
| 符号 |
GHS02, GHS06 |
信号词 | Danger |
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Hydrolytic pathway of 5-fluorouracil in aqueous solutions for clinical use.
J. Pharm. Biomed. Anal. 98 , 446-62, (2014) The purpose of the study was to investigate the degradation pathway of 5-fluorouracil (FU) in the situation of commercial formulations for clinical use, namely FU dissolved in sodium hydroxide (NaOH) solutions or Tris buffer at pH 8.5-9. Combination of data f... |
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Measuring the relative hydrogen-bonding strengths of alcohols in aprotic organic solvents.
ChemPhysChem 16(1) , 160-8, (2015) Voltammetric experiments with 9,10-anthraquinone and 1,4-benzoquinone performed under controlled moisture conditions indicate that the hydrogen-bond strengths of alcohols in aprotic organic solvents can be differentiated by the electrochemical parameter ΔEp (... |
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2-Halogeno-ethanols as an uncoupler of phosphorylation in rat liver mitochondria.
Experientia 36(5) , 537-9, (1980) 2-Chloroethanol, 2-bromoethanol and 2,2,2-trifluoroethanol at a concentration of 0.79 vol.% stimulated state 4 respiration and released oligomycin inhibition of state 3 respiration. 2-Fluoroethanol and 1-propanol at the same concentration did not affect the r... |
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2-halogeno-ethanols as denaturant of protein. Activity coefficient of N-acetyl ethyl esters of aromatic amino acids in 2-fluoroethanol, 2,2,2-trifluoroethanol, 2-chloroethanol, 2-bromoethanol, 1-propanol, and ethanol.
Fukushima J. Med. Sci. 28(3-4) , 83-92, (1982)
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An automatic method to generate force-field parameters for hetero-compounds.
Acta Crystallogr. D Biol. Crystallogr. 59(Pt 2) , 274-89, (2003) A program, Hess2FF, has been developed that automatically constructs parameter and topology files to be used in crystallographic refinement for any molecule, based on a Hessian (force-constant) matrix estimated by any method. The program is tested by redefini... |
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Tailoring the key in a molecular lock-and-key model system: the propylene oxide...2-fluoroethanol complex.
J. Am. Chem. Soc. 130(18) , 5916-21, (2008) The conformational isomerism of the propylene oxide (PO)...2-fluoroethanol (FE) complex has been investigated using molecular beam Fourier-transform microwave spectroscopy complemented with high level ab initio calculations. Rotational transitions of three di... |
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Effects of ethanol and its fluorinated analogues on the calcium ATPase of sarcoplasmic reticulum.
Biochem. Int. 26(6) , 979-85, (1992) The effects of ethanol, monofluoro- and trifluoroethanol on the hydrolysis of ATP and coupled Ca2+ translocation by sarcoplasmic reticulum Ca(2+)-ATPase (EC 3.6.1.38) were measured. All three alcohols had parallel effects on the enzyme activities at concentra... |
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Enzymatic defluorination and metabolism of fluoroacetate, fluoroacetamide, fluoroethanol, and (-)-erythro-fluorocitrate in rats and mice examined by 19F and 13C NMR.
Chem. Res. Toxicol. 2(6) , 429-35, (1989) Fluoroacetate administered intraperitoneally (ip) to rats and mice is defluorinated to give fluoride ion evident in urine and kidney by 19F NMR. The use of [2-13C]-, [1,2-13C]-, and [1,2-14C]fluoroacetate, prepared from isotopically labeled glycine, combined ... |
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Molecular self-recognition: rotational spectra of the dimeric 2-fluoroethanol conformers.
Chemistry 15(1) , 270-7, (2009) Fluoroalcohols show competitive formation of intra- and intermolecular hydrogen bonds, a property that may be crucial for the protein-altering process in a fluoroalcohol/water solution. In this study, we examine the intra- and intermolecular interactions of 2... |
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Preparation and preliminary biodistribution of "no carrier added" fluorine1-8 fluoroethanol.
J. Nucl. Med. 21(6) , 559-64, (1980) No-carrier-added [18F] fluoroethanol has been prepared by two routes. The first involves fluoride-ion displacement on alpha-p-toluene sulfonyl ethyl glycolate followed by reduction of the alpha-fluoroethyl acetate. The second involves a ring-opening reaction ... |