SnAP OA Reagent
SnAP OA Reagent结构式
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常用名 | SnAP OA Reagent | 英文名 | 3-[(Tributylstannyl)methoxy]-1-propanamine |
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| CAS号 | 1577233-70-5 | 分子量 | 378.18 | |
| 密度 | 1.102 at 25℃ | 沸点 | 387.6±48.0 °C at 760 mmHg | |
| 分子式 | C16H37NOSn | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 188.2±29.6 °C | |
| 符号 |
GHS06, GHS09 |
信号词 | Danger |
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SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.
Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)
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SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.
Nature Chemistry 6(4) , 310-4, (2014) Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially medium-sized rings, are limited. We describe the developmen... |
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One-step synthesis of saturated spirocyclic N-heterocycles with stannyl amine protocol (SnAP) reagents and ketones.
J. Am. Chem. Soc. 136(51) , 17726-9, (2014) The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions. The resulting, N-unprotected spirocyclic amines are in great demand as scaffolds for dru... |
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SnAP reagents for the synthesis of piperazines and morpholines.
Org. Lett. 16(4) , 1236-9, (2014) Substituted piperazines and morpholines are valuable structural motifs in biologically active compounds, but are not easily prepared by contemporary cross-coupling approaches. In this report, we introduce SnAP reagents for the transformation of aldehydes into... |