对三氟甲基苯甲醛
对三氟甲基苯甲醛结构式
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常用名 | 对三氟甲基苯甲醛 | 英文名 | 4-(Trifluoromethyl)benzaldehyde |
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| CAS号 | 455-19-6 | 分子量 | 174.120 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 176.4±0.0 °C at 760 mmHg | |
| 分子式 | C8H5F3O | 熔点 | 1-2°C | |
| MSDS | 中文版 美版 | 闪点 | 65.6±0.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Ph3As-catalyzed wittig-type olefination of aldehydes with diazoacetate in the presence of Na2S2O4.
J. Org. Chem. 72 , 6628, (2007) In the presence of sodium hydrosulfite and a catalytic amount of AsPh3 and Fe(TCP)Cl, aldehydes react with ethyl diazoacetate to give the corresponding alpha,beta-unsaturated esters in high yields with excellent stereoselectivities (E/Z > 50/1). |
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Determination of the equilibrium distibution between alcohol and aldehyde substrates when bound to horse liver alcohol dehydrogenase using magnetic resonance.
Biochemistry 19(24) , 5486-93, (1980) The interactions of horse liver alcohol dehydrogenase (LADH) with the rho-trifluoromethyl derivatives of benzyl alcohol, benzaldehyde, and benzoic acid have been investigated by use of 19F nuclear magnetic resonance. The aldehyde and alcohol are good substrat... |
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19F nuclear magnetic resonance observations of aldehyde dismutation catalyzed by horse liver alcohol dehydrogenase.
Arch. Biochem. Biophys. 217(1) , 226-35, (1982)
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J. Am. Chem. Soc. 115 , 8570, (1993)
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Tetrahedron Lett. 34 , 1925, (1993)
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Tetrahedron Asymmetry 5 , 411, (1994)
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Tetrahedron 49 , 9613, (1993)
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Synthesis and properties of new pyridine-bridged poly (ether-imide) s based on 4-(4-trifluoromethylphenyl)-2, 6-bis [4-(4-aminophenoxy) phenyl] pyridine.
J. Fluor. Chem. 129(1) , 56-63, (2008)
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