2-甲基乙酰乙酸乙酯
2-甲基乙酰乙酸乙酯结构式
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常用名 | 2-甲基乙酰乙酸乙酯 | 英文名 | Ethyl 2-methylacetoacetate |
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| CAS号 | 609-14-3 | 分子量 | 144.168 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 185.8±8.0 °C at 760 mmHg | |
| 分子式 | C7H12O3 | 熔点 | -45 °C | |
| MSDS | 中文版 美版 | 闪点 | 68.9±18.5 °C |
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Asymmetric reduction of ethyl 2-methyl 3-oxobutanoate by Chlorella.
Biosci. Biotechnol. Biochem. 63(3) , 598-601, (1999) Chlorella pyrenoidosa Chick reduced ethyl 2-methyl 3-oxobutanoate to the corresponding alcohols with the diastereomer (anti/syn) ratio of 53/47. The enantiomer excesses of anti-(2S, 3S)- and syn-(2S, 3R)-hydroxy esters were 89 and > 99ee% respectively. C. vul... |
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Asymmetric reduction of ethyl 2-methyl e-oxobutanoate by fungi.
Biosci. Biotechnol. Biochem. 64(1) , 194-7, (2000) Seven fungi, which are found to reduce ethyl 3-oxobutanoate in high yields, were tested for their reducing ability for ethyl 2-methyl 3-oxobutanoate. We obtained some interesting findings. In particular, Penicillium purpurogenum reduced ethyl 2-methyl 3-oxobu... |
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