Ethyl 2-methylacetoacetate
Ethyl 2-methylacetoacetate structure
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Common Name | Ethyl 2-methylacetoacetate | ||
|---|---|---|---|---|
| CAS Number | 609-14-3 | Molecular Weight | 144.168 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 185.8±8.0 °C at 760 mmHg | |
| Molecular Formula | C7H12O3 | Melting Point | -45 °C | |
| MSDS | Chinese USA | Flash Point | 68.9±18.5 °C | |
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Asymmetric reduction of ethyl 2-methyl 3-oxobutanoate by Chlorella.
Biosci. Biotechnol. Biochem. 63(3) , 598-601, (1999) Chlorella pyrenoidosa Chick reduced ethyl 2-methyl 3-oxobutanoate to the corresponding alcohols with the diastereomer (anti/syn) ratio of 53/47. The enantiomer excesses of anti-(2S, 3S)- and syn-(2S, 3R)-hydroxy esters were 89 and > 99ee% respectively. C. vul... |
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Asymmetric reduction of ethyl 2-methyl e-oxobutanoate by fungi.
Biosci. Biotechnol. Biochem. 64(1) , 194-7, (2000) Seven fungi, which are found to reduce ethyl 3-oxobutanoate in high yields, were tested for their reducing ability for ethyl 2-methyl 3-oxobutanoate. We obtained some interesting findings. In particular, Penicillium purpurogenum reduced ethyl 2-methyl 3-oxobu... |
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