过氧化十二酰
一般危化品
过氧化十二酰结构式
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常用名 | 过氧化十二酰 | 英文名 | dilauroyl peroxide |
|---|---|---|---|---|
| CAS号 | 105-74-8 | 分子量 | 398.620 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 467.3±28.0 °C at 760 mmHg | |
| 分子式 | C24H46O4 | 熔点 | 53-57 °C(lit.) | |
| MSDS | 美版 | 闪点 | 194.9±24.0 °C | |
| 符号 |
GHS02 |
信号词 | Danger |
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Comparison on photo-initiators for the preparation of methacrylate monolithic columns for capillary electrochromatography
J. Chromatogr. A. 1217(19) , 3231-7, (2010) The synthesis of lauryl methacrylate monoliths for capillary electrochromatography by UV polymerization using several free-radical initiators (α,α′-azobisisobutyronitrile, 2,2-dimethoxy-2-phenylacetophenone, dibenzoyl peroxide (BPO) and lauroyl peroxide (LPO)... |
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Photo-polymerized lauryl methacrylate monolithic columns for CEC using lauroyl peroxide as initiator.
Electrophoresis 30(21) , 3748-56, (2009) Lauryl methacrylate (LMA)-ester based monolithic columns photo-polymerized using lauroyl peroxide (LPO) as initiator were prepared, and their morphological and CEC properties were studied. The composition of the polymerization mixture (i.e. ratios of monomers... |
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Chemical initiation for butyl and lauryl acrylate monolithic columns for CEC.
Electrophoresis 30(4) , 599-606, (2009) Butyl acrylate (BA)- and lauryl acrylate (LA)-based monolithic stationary phases for CEC were synthesized, using a redox system as initiator of polymerization. BA monoliths were initiated with ammonium peroxodisulfate, whereas LA columns were obtained with la... |
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Lauroyl peroxide.
IARC Monogr. Eval. Carcinog. Risk Chem. Hum. 36 , 315-21, (1985)
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Lauroyl peroxide.
IARC Monogr. Eval. Carcinog. Risks Hum. 71 Pt 3 , 1485-7, (1999)
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Effects of peroxides on rodent skin: epidermal hyperplasia and tumor promotion.
J. Invest. Dermatol. 79(1) , 30-4, (1982) Free radical generating peroxides are potent skin irritants. After a single topical application of either 10, 20, or 40 mg of lauroyl peroxides or benzoyl peroxide on the dorsal skin of Sencar mice, the epidermal thickness increased markedly. No major inflamm... |
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Protective effect of quercetin and rutin on photosensitized lysis of human erythrocytes in the presence of hematoporphyrin.
Biochim. Biophys. Acta 799(3) , 313-7, (1984) Photosensitized hemolysis of human erythrocytes by hematoporphyrin was suppressed by flavonols such as quercetin and rutin at submillimolar concentrations. The suppression of photohemolysis was accompanied by inhibition of lipid peroxidation by the reagents. ... |
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Lauroyl peroxide as thermal initiator of lauryl methacrylate monolithic columns for CEC.
Electrophoresis 29(21) , 4399-406, (2008) The preparation of lauryl methacrylate (LMA)-based monolithic columns for CEC using lauroyl peroxide (LPO) as thermal initiator of polymerization has been investigated. The influence of initiator amount and composition of porogenic solvent on the physical and... |
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The reactivity of 1,3-butadiene with butadiene-derived popcorn polymer.
J. Hazard. Mater. 115(1-3) , 71-90, (2004) Adiabatic calorimetry performed on butadiene-derived popcorn polymer samples from industrial facilities has revealed exothermic behavior accompanied by non-condensible gas production, indicative of possible decomposition, at elevated temperatures. In the pres... |
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Synthesis of (2-alkylthiothiazolin-5-yl)methyl dodecanoates via tandem radical reaction.
Org. Biomol. Chem. 11(33) , 5481-90, (2013) A series of (2-alkylthiothiazolin-5-yl)methyl dodecanoates was synthesized from various alkyl N-allylcarbamodithioates and dilauroyl peroxide via a tandem radical hydrogen-abstraction-cyclization-substitution/combination reaction with a 5-exo-trig radical cyc... |