苯亚砜甲酯
苯亚砜甲酯结构式
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常用名 | 苯亚砜甲酯 | 英文名 | methyl phenyl sulfoxide |
|---|---|---|---|---|
| CAS号 | 1193-82-4 | 分子量 | 140.20300 | |
| 密度 | N/A | 沸点 | 139-140 °C14 mm Hg(lit.) | |
| 分子式 | C7H8OS | 熔点 | 26-29 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 187 °F | |
| 符号 |
GHS05, GHS07 |
信号词 | Danger |
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Murraya koenigii leaf extract inhibits proteasome activity and induces cell death in breast cancer cells.
BMC Complement Altern. Med. 13 , 7, (2013) Inhibition of the proteolytic activity of 26S proteasome, the protein-degrading machine, is now considered a novel and promising approach for cancer therapy. Interestingly, proteasome inhibitors have been demonstrated to selectively kill cancer cells and also... |
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Resolution of racemic sulfoxides with high productivity and enantioselectivity by a Rhodococcus sp. strain as an alternative to biooxidation of prochiral sulfides for efficient production of enantiopure sulfoxides.
Bioresour. Technol. 102(2) , 1537-42, (2011) Whole cells of Rhodococcus sp. ECU0066 were used a catalyst for resolution of racemic sulfoxides, as an alternative to asymmetric oxidation of sulfides for efficient production of enantiopure sulfoxides. Racemic sulfoxides were excellent substrates for biotra... |
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Biocatalytic oxidation by chloroperoxidase from Caldariomyces fumago in polymersome nanoreactors.
Org. Biomol. Chem. 7 , 4604-4610, (2009) The encapsulation of chloroperoxidase from Caldariomyces fumago (CPO) in block copolymer polymersomes is reported. Fluorescence and electron microscopy show that when the encapsulating conditions favour self-assembly of the block copolymer, the enzyme is inco... |
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Synthesis, characterization, reactivity, and catalytic potential of model vanadium(IV, V) complexes with benzimidazole-derived ONN donor ligands.
Inorg. Chem. 45(15) , 5924-37, (2006) Reaction between [VO(acac)(2)] and the ONN donor Schiff base Hsal-ambmz (I) (Hsal-ambmz = Schiff base obtained by the condensation of salicylaldehyde and 2-aminomethylbenzimidazole) resulted in the formation of the complexes [V(IV)O(acac)(sal-ambmz)] (1), [V(... |
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Hydrogen bonding. 32. An analysis of water-octanol and water-alkane partitioning and the delta log P parameter of seiler.
J. Pharm. Sci. 83 , 1085, (1994) A general linear solvation energy equation has been used to analyze published partition coefficients in the systems water-octanol (613 solutes), water-hexadecane (370 solutes), water-alkane (200 solutes), and water-cyclohexane (170 solutes). The descriptors u... |
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Asymmetric synthesis of the potent HIV-protease inhibitor, nelfinavir.
J. Org. Chem. 75(2) , 498-501, (2010) An asymmetric synthesis of nelfinavir is described starting from acrolein and (S)-methyl phenyl sulfoxide. The key features include (a) stereoselective preparation of a beta-protected amino-gamma,delta-unsaturated sulfoxide by the reaction of an alpha-sulfiny... |
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Synthesis of isotopically labeled 1,3-dithiane.
J. Labelled Comp. Radiopharm. 57(5) , 338-41, (2014) The 1,3-dithiane is a protected formaldehyde anion equivalent that could serve as a useful labeled synthon. We report a facile synthesis of 1,3-[2-(13)C]- and 1,3-[2-(13)C, 2-(2)H2]dithiane in two steps from [(13)C]- or [(13) C, (2)H3 ]methyl phenyl sulfoxide... |
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Cortactin and dynamin are required for the clathrin-independent endocytosis of gammac cytokine receptor.
J. Cell Biol. 168 , 155-63, (2005) Endocytosis is critical for many cellular functions. We show that endocytosis of the common gammac cytokine receptor is clathrin independent by using a dominant-negative mutant of Eps15 or RNA interference to knock down clathrin heavy chain. This pathway is s... |
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Solute-solvent interactions and chiral induction in liquid crystals.
J. Am. Chem. Soc. 127(33) , 11736-44, (2005) The induction of a cholesteric phase by doping an achiral nematic liquid crystal with an enantiopure solute is a phenomenon that, as in all general supramolecular phenomena of chiral amplification, depends in a subtle way on intermolecular interactions. The m... |
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Formation of compound I in the reaction of native myoglobins with hydrogen peroxide.
J. Biol. Chem. 275(45) , 34858-66, (2000) Reaction of ferric native myoglobin (Mb) with hydrogen peroxide (H(2)O(2)) was studied by the aid of stopped-flow rapid-scan spectrophotometry. In contrast to the results in previous studies where compound I was reported to be undetectable, both sperm whale a... |