巴豆酸甲酯
一般危化品
巴豆酸甲酯结构式
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常用名 | 巴豆酸甲酯 | 英文名 | Methyl (2E)-2-butenoate |
|---|---|---|---|---|
| CAS号 | 623-43-8 | 分子量 | 100.116 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 121.0±0.0 °C at 760 mmHg | |
| 分子式 | C5H8O2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 4.4±0.0 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Danger |
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First total syntheses of the phytotoxins solanapyrones D and E via the domino Michael protocol.
J. Org. Chem. 67(17) , 5969-76, (2002) The phytotoxins solanapyrones D (1) and E (2) have been synthesized from the decalone prepared by the domino Michael reaction of the kinetic enolate of optically pure acetylcyclohexene with methyl crotonate. The decalone was transformed into a solanapyrone co... |
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The vinylogous aldol reaction of unsaturated esters and enolizable aldehydes using the novel Lewis acid aluminum tris(2,6-di-2-naphthylphenoxide).
Org. Lett. 14(11) , 2678-81, (2012) The synthesis of the novel Lewis acid, aluminum tris(2,6-di-2-naphthylphenoxide) (ATNP), and its use in the vinylogous aldol reaction between methyl crotonate and enolizable aldehydes are described. ATNP is related to Yamamoto's Lewis acid, aluminum tris(2,6-... |
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Solvent engineering: an effective tool to direct chemoselectivity in a lipase-catalyzed Michael addition. Priego J, et al.
Tetrahedron 65(2) , 536-539, (2009)
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