三苯基氯甲烷
三苯基氯甲烷结构式
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常用名 | 三苯基氯甲烷 | 英文名 | Triphenylmethyl Chloride |
|---|---|---|---|---|
| CAS号 | 76-83-5 | 分子量 | 278.775 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 230-235 ºC (20 mmHg) | |
| 分子式 | C19H15Cl | 熔点 | 110-113 ºC | |
| MSDS | 中文版 美版 | 闪点 | 177.9±12.0 °C | |
| 符号 |
GHS05 |
信号词 | Danger |
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Structure-activity relationship of S-trityl-L-cysteine analogues as inhibitors of the human mitotic kinesin Eg5.
J. Med. Chem. 51 , 1115-25, (2008) The human kinesin Eg5 is a potential drug target for cancer chemotherapy. Eg5 specific inhibitors cause cells to block in mitosis with a characteristic monoastral spindle phenotype. Prolonged metaphase block eventually leads to apoptotic cell death. S-trityl-... |
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Thermally robust and porous noncovalent organic framework with high affinity for fluorocarbons and CFCs.
Nat. Commun. 5 , 5131, (2014) Metal-organic and covalent organic frameworks are porous materials characterized by outstanding thermal stability, high porosities and modular synthesis. Their repeating structures offer a great degree of control over pore sizes, dimensions and surface proper... |
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Comparative susceptibility of newborn and young rats to six industrial chemicals.
Congenit. Anom. (Kyoto.) 45(4) , 137-45, (2005) To elucidate the comparative susceptibility of newborn rats to chemicals, newborn and young animals were administered six industrial chemicals by gavage from postnatal days (PND) 4 to 21, and for 28 days starting at 5-6 weeks of age respectively, under the sa... |
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Inhibition of intercellular junctional communication in human fibroblasts by triphenylmethane, triphenylmethylchloride, tetraphenylboron and related compounds.
Biochim. Biophys. Acta 847(1) , 1-7, (1985) Hydroxylated 4-thiaflavans, possessing the antioxidant features of catechol containing flavonoids and/or tocopherols, were evaluated as protective agents against oxidation damage induced in herring sperm DNA by cumene hydroperoxide (CumOOH) or by the glutathi... |
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Method for activation and recycling of trityl resins.
J. Org. Chem. 77(16) , 7071-5, (2012) This note describes a rapid and mild strategy for the loading of alcohols and anilines onto a polystyrene triphenylmethyl (trityl) resin. High loadings were obtained in a matter of minutes by treating resin-bound trityl chloride with triethyloxonium tetrafluo... |
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Pediatric susceptibility to 18 industrial chemicals: a comparative analysis of newborn with young animals.
Regul Toxicol Pharmacol 47(3) , 296-307, (2007) We comprehensively re-analyzed the toxicity data for 18 industrial chemicals from repeated oral exposures in newborn and young rats, which were previously published. Two new toxicity endpoints specific to this comparative analysis were identified, the first, ... |
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Chlorodecarboxylation of 17 beta-acetoxy-3-methoxy-9-oxo-9, 11-secoestra-1, 3, 5 (10)-trien-11-oic acid with lead tetraacetate and trityl chloride.
Steroids 39(5) , 537-45, (1982)
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Im-trityl protection of histidine.
J. Pept. Sci. 5(8) , 368-73, (1999) A rational attempt to prepare FmocHis(piTrt)OH regiospecifically gave in fact the well-known tau-trityl isomer, and experiments with model systems indicate that the prospects for access to pi-trityl histidine derivatives, which would be of great value for the... |
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Oxidation studies on Andrographolide.
Nat. Prod. Res. 20(12) , 1053-8, (2006) Jones oxidation of Andrographolide (1), gave mixture of three products (3-dehydroandrographolide (5), 3,19-bis dehydroandrographolide (6) and 19-dehydroandrographolide (7). Tritylation of andrographolide at C19-OH resulted to products 8 and diene 9, which can... |
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V. Kohli et al.
Tetrahedron Lett. and references cited therein 21 , 2683, (1980)
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