亚磷酸二乙酯
亚磷酸二乙酯结构式
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常用名 | 亚磷酸二乙酯 | 英文名 | Diethyl phosphite |
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| CAS号 | 762-04-9 | 分子量 | 138.10200 | |
| 密度 | 1.072 g/mL at 25 °C(lit.) | 沸点 | 50-51 °C2 mm Hg(lit.) | |
| 分子式 | C4H11O3P | 熔点 | -70 °C | |
| MSDS | 中文版 美版 | 闪点 | 180 °F | |
| 符号 |
GHS07 |
信号词 | Warning |
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Silver-catalyzed radical phosphonofluorination of unactivated alkenes.
J. Am. Chem. Soc. 135(38) , 14082-5, (2013) We report herein a mild and catalytic phosphonofluorination of unactivated alkenes. With catalysis by AgNO3, the condensation of various unactivated alkenes with diethyl phosphite and Selectfluor reagent in CH2Cl2/H2O/HOAc at 40 °C led to the efficient synthe... |
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Efficient cross-coupling of functionalized arylzinc halides catalyzed by a nickel chloride-diethyl phosphite system.
Org. Lett. 7(22) , 4871-4, (2005) [reaction: see text] The combination of diethyl phosphite and DMAP as ligands for nickel in an 8:1 THF-N-ethylpyrrolidinone (NEP) mixture allows a very efficient cross-coupling reaction to be performed between various functionalized arylzinc halides and aryl ... |
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A method for synthesis of homoallylic bromide.
J. Org. Chem. 78(12) , 5918-24, (2013) Cyclopropyl Grignard reagents react with carbonyl compounds in the presence of diethyl phosphite to give homoallylic bromides. The reaction is effectively carried out under mild conditions in a one-pot fashion with moderate to good yields. |
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Synthesis and antiproliferative activity of novel α-aminophosphonates.
Chem. Pharm. Bull. 60(12) , 1531-7, (2012) A novel series of carbazole-based α-aminophosphonates were synthesized by three component coupling of 6-bromo-9-ethyl-9H-carbazole-3-carbaldehyde, amine and diethyl phosphite using polyethylene glycol (PEG-400) as a green reaction media. The antiproliferative... |
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Using metal complex ion-molecule reactions in a miniature rectilinear ion trap mass spectrometer to detect chemical warfare agents.
J. Am. Soc. Mass Spectrom. 24(6) , 917-25, (2013) The gas-phase reactions of a series of coordinatively unsaturated [Ni(L)n](y+) complexes, where L is a nitrogen-containing ligand, with chemical warfare agent (CWA) simulants in a miniature rectilinear ion trap mass spectrometer were investigated as part of a... |