4-氨基七氟甲苯
4-氨基七氟甲苯结构式
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常用名 | 4-氨基七氟甲苯 | 英文名 | 4-aminoheptafluorotoluene |
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| CAS号 | 651-83-2 | 分子量 | 233.086 | |
| 密度 | 1.6±0.1 g/cm3 | 沸点 | 171.7±40.0 °C at 760 mmHg | |
| 分子式 | C7H2F7N | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 67.9±18.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Pd(II)-catalyzed carbonylation of C(sp3)-H bonds: a new entry to 1,4-dicarbonyl compounds.
J. Am. Chem. Soc. 49th ed., 132 , 17378-17380, (2010) Pd(II)-catalyzed β-C(sp(3))-H carbonylation of N-arylamides under CO (1 atm) has been achieved. Following amide-directed C(sp(3))-H cleavage and insertion of CO into the resulting [Pd(II)-C(sp(3))] bond, intramolecular C-N reductive elimination gave the corre... |
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Pd-catalyzed intermolecular C-H amination with alkylamines.
J. Am. Chem. Soc. 20th ed., 133 , 7652-7655, (2011) C-H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved with either Pd(II) or Pd(0) catalysts. Furthermore, we demonstrate that secondary amines can be directly used with benzoyl peroxide in a one-pot procedure that proceeds via the... |
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Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes.
J. Am. Chem. Soc. 49th ed., 133 , 19598-19601, (2011) Systematic ligand development has led to the identification of novel mono-N-protected amino acid ligands for Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes. A diverse range of organoboron reagents can be used as coupling partners, and the r... |
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Wasa, M; et. al.
J. Am. Chem. Soc. 132(11) , 3680-3681
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Palladium(0)-Catalyzed Alkynylation of C(sp3)-H Bonds He, J.: et. al.
J. Am. Chem. Soc.
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