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18687-43-9

18687-43-9结构式
18687-43-9结构式
品牌特惠专场
常用名 18687-43-9 英文名 Isopentenyl pyrophosphate trilithium salt
CAS号 18687-43-9 分子量 263.89100
密度 N/A 沸点 N/A
分子式 C5H9Li3O7P2 熔点 N/A
MSDS 中文版 美版 闪点 N/A
符号 GHS07
GHS07
信号词 Warning

An improved synthesis of isopentenyl pyrophosphate.

Biochem. J. 105 , 545-547, (1967)

1. Isopentenol was converted into isopentenyl phosphate with phosphoryl chloride in ether containing pyridine. 2. The isopentenyl phosphate reacted in 2-methylpropan-2-ol-water with morpholine and dicyclohexylcarbodi-imide to give isopentenyl phosphoromorphol...

The biosynthesis of rubber. Incorporation of mevalonate and isopentenyl pyrophosphate into rubber by Hevea brasiliensis-latex fractions.

Biochem. J. 89(3) , 565-74, (1963)

The biosynthesis of isoprenoids and the mechanisms regulating it in plants.

Biosci. Biotechnol. Biochem. 75 , 1219-1225, (2011)

Plants synthesize isopentenyl diphosphate (IPP) via the mevalonate pathway and the methylerythritol phosphate (MEP) pathway. IPP is condensed to its allylic isomer, dimethylallyl diphosphate, to yield geranylgeranyl diphosphate, a common precursor for the pro...

Type-2 isopentenyl diphosphate isomerase: evidence for a stepwise mechanism.

J. Am. Chem. Soc. 133 , 19017-19019, (2011)

Isopentenyl diphosphate isomerase (IDI) catalyzes the interconversion of isopentenyl diphosphate (IPP) and dimethylallyl diphosphate (DMAPP). These two molecules are the building blocks for construction of isoprenoid carbon skeletons in nature. Two structural...

Type II isopentenyl diphosphate isomerase: probing the mechanism with alkyne/allene diphosphate substrate analogues.

Biochemistry 49 , 6228-6233, (2010)

Isopentenyl diphosphate isomerase (IDI) catalyzes the interconversion of isopentenyl diphosphate (IPP) and dimethylallyl diphosphate (DMAPP), the basic five-carbon building blocks of isoprenoid molecules. Two structurally unrelated classes of IDIs are known. ...

Isopentenyl diphosphate isomerase catalyzed reactions in D2O: product release limits the rate of this sluggish enzyme-catalyzed reaction.

J. Am. Chem. Soc. 134 , 6568-6570, (2012)

The E. coli isopentenyl diphosphate isomerase (IDI) catalyzed reaction of isopentenyl diphosphate (IPP) in D(2)O gives a 66% yield of dimethylallyl diphosphate labeled with deuterium at the (E)-methyl group (d-DMAPP) and a 34% yield of IPP labeled with 1 mol ...

New aspects of rubber biosynthesis. Archer B L and Audrey B G

Bot. J. Linn. Soc. 94 , 181-196, (1987)