![]() 1,3-二硫戊环-2-羧酸乙酯结构式
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常用名 | 1,3-二硫戊环-2-羧酸乙酯 | 英文名 | ethyl 1,3-dithiolane-2-carboxylate |
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CAS号 | 20461-99-8 | 分子量 | 178.27200 | |
密度 | 1.249 g/mL at 25 °C(lit.) | 沸点 | 85 °C0.1 mm Hg(lit.) | |
分子式 | C6H10O2S2 | 熔点 | N/A | |
MSDS | 美版 | 闪点 | >230 °F |
General strategy for the syntheses of corynanthe, tacaman, and oxindole alkaloids.
J. Org. Chem. 71(17) , 6547-61, (2006) We report herein the total synthesis of the corynanthe alkaloid dihydrocorynantheol and the formal syntheses of the indole alkaloids tacamonine, rhynchophylline, and hirsutine. The strategies for assembling the corynanthe and tacaman skeletal frameworks compr... |
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Stereodivergent synthesis of enantiopure cis- and trans-3-Ethyl-4-piperidineacetates.
Org. Lett. 4(16) , 2787-90, (2002) [reaction: see text] Starting from a common chiral bicyclic lactam 11, enantiopure trans- or cis-3-ethyl-4-piperidineacetate derivatives are obtained by conjugate addition of an enolate or a cuprate to the unsaturated lactams 12 or 18, respectively. |
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H. Paulson, W. Koebernick
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M. Kato et al.
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L.A. Flippin, M.A. Dombroski
Tetrahedron Lett. 26 , 2977, (1985)
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