碘化亚铜
碘化亚铜结构式
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常用名 | 碘化亚铜 | 英文名 | Copper(I) iodide |
|---|---|---|---|---|
| CAS号 | 7681-65-4 | 分子量 | 190.451 | |
| 密度 | 5.62 g/mL at 25 °C(lit.) | 沸点 | 1290 °C | |
| 分子式 | CuI | 熔点 | 605 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 1290°C | |
| 符号 |
GHS05, GHS07, GHS09 |
信号词 | Danger |
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Expedient synthesis of tetrasubstituted pyrroles via a copper-catalyzed cascade inter-/intramolecular cyclization of 1,3-enynes carry a nitro group with amines.
Org. Biomol. Chem. 13(9) , 2786-92, (2015) Various tetrasubstituted pyrroles/pyrazoles have been prepared from nitro-substituted 1,3-enynes with aromatic amines/hydrazines via a copper-catalyzed cascade aza-Michael addition, cyclization and aromatization at room temperature. This protocol is also effe... |
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Facilitated preparation of bioconjugatable zwitterionic quantum dots using dual-lipid encapsulation.
J. Colloid. Interface Sci. 437 , 140-6, (2014) Zwitterionic quantum dots prepared through incorporated zwitterionic ligands on quantum dot surfaces, are being paid significant attention in biomedical applications because of their excellent colloidal stability across a wide pH and ionic strength range, ant... |
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Hepatic oxidative status and metal homeostasis disturbance of 2-hydroxylated dioxin in ICR mice.
Environ. Toxicol. Pharmacol. 38(3) , 881-90, (2014) In the present study, the toxic effects of the oral exposure of 2-hydroxylated dioxin (2-HODD) in ICR male mice were examined. The mice were administered different doses (0.2, 2.0 and 20.0mg/kg) of 2-HODD. After 14 days of exposure, the oxidative stress (OS) ... |
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Nanoscale metallogel via self-assembly of self-assembled trinuclear coordination rings: multi-stimuli-responsive soft materials.
Dalton Trans. 44 , 15181-8, (2015) A rare variety of coordination rings having the M3L6 composition are prepared by the combination of Pd(NO3)2 with an imidazolyl or benzimidazolyl appended bidentate non-chelating ligand (i.e.L1 or L2). The variable concentration 1H NMR spectra of the trinucle... |
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Highly Efficient Copper-Indium-Selenide Quantum Dot Solar Cells: Suppression of Carrier Recombination by Controlled ZnS Overlayers.
ACS Nano 9 , 11286-95, (2015) Copper-indium-selenide (CISe) quantum dots (QDs) are a promising alternative to the toxic cadmium- and lead-chalcogenide QDs generally used in photovoltaics due to their low toxicity, narrow band gap, and high absorption coefficient. Here, we demonstrate that... |
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Experimental investigation on the soil sorption properties and hydrophobicity of polymethoxylated, polyhydroxylated diphenyl ethers and methoxylated-, hydroxylated-polychlorinated diphenyl ethers.
Chemosphere 134 , 84-90, (2015) In the present study, twenty-six types of polymethoxylated diphenyl ethers (PMeODEs), twenty types of polyhydroxylated diphenyl ethers (PHODEs), seven types of methoxylated-polychlorinated diphenyl ethers (MeO-PCDEs) and seven types of hydroxylated-polychlori... |
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CuI-mediated sequential iodination/cycloetherification of o-arylphenols: synthesis of 2- or 4-iododibenzofurans and mechanistic studies.
Org. Lett. 14(20) , 5362-5, (2012) An efficient synthesis of 2- or 4-iododibenzofurans through CuI-mediated sequential iodination/cycloetherification of two aromatic C-H bonds in o-arylphenols has been developed. Both the preexisting electron-withdrawing groups (NO(2), CN, and CHO) and the new... |
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A Programmed DNA Marker Based on Bis(4-ethynyl-1,8-naphthalimide) and Three-Methane-Bridged Thiazole Orange.
Chemistry 21 , 16623-30, (2015) Two large conjugated naphthalimide derivatives with or without three-methane-bridged thiazole orange (TO3; i.e., compounds 1 a and 2 a, respectively) were designed and synthesized. The fluorescence of the naphthalimide group in compound 1 a at λ=532 nm initia... |
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Highly efficient Cu(I)-catalyzed oxidation of alcohols to ketones and aldehydes with diaziridinone.
Org. Lett. 15(5) , 992-5, (2013) A novel and efficient Cu(I)-catalyzed oxidation of alcohols has been achieved with di-tert-butyldiaziridinone as the oxidant under mild conditions. A wide variety of primary and secondary alcohols with various functional groups can be oxidized to aldehydes an... |
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Synthesis of phenothiazines via ligand-free CuI-catalyzed cascade C-S and C-N coupling of aryl ortho-dihalides and ortho-aminobenzenethiols.
Chem. Commun. (Camb.) 48(43) , 5367-9, (2012) A ligand-free CuI-catalyzed cascade C-S and C-N cross coupling of (hetero)aryl ortho-dihalides and ortho-aminobenzenethiols has been developed, and various phenothiazines were synthesized with excellent regioselectivity. A possible mechanism is proposed for t... |