氯[(1,2,3-)-3-苯基-2-丙烯基][1,3-双(2,6-二-I-丙基苯基)咪唑-2-基]钯(II)
![氯[(1,2,3-)-3-苯基-2-丙烯基][1,3-双(2,6-二-I-丙基苯基)咪唑-2-基]钯(II)结构式](https://image.chemsrc.com/caspic/165/884879-23-6.png)
氯[(1,2,3-)-3-苯基-2-丙烯基][1,3-双(2,6-二-I-丙基苯基)咪唑-2-基]钯(II)结构式
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常用名 | 氯[(1,2,3-)-3-苯基-2-丙烯基][1,3-双(2,6-二-I-丙基苯基)咪唑-2-基]钯(II) | 英文名 | phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii) |
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| CAS号 | 884879-23-6 | 分子量 | 647.62900 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C36H45ClN2Pd | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Room-temperature Suzuki-Miyaura couplings in water facilitated by nonionic amphiphiles.
Org. Lett. 10 , 1333, (2008) Use of a dilute aqueous solution containing a nonionic amphiphile allows efficient Suzuki-Miyaura cross-couplings of arylboronic acids with a wide array of aryl halides and pseudohalides, including sterically hindered and lipophilic substrates, in most cases ... |
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Modified (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes for room-temperature Suzuki-Miyaura and Buchwald-Hartwig reactions.
J. Am. Chem. Soc. 128 , 4101, (2006) A series of (NHC)Pd(R-allyl)Cl complexes [NHC: IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, SIPr = N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene; R = H, Me, gem-Me2, Ph] have been synthesized and fully characterized. When compared ... |
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Rapid room temperature Buchwald-Hartwig and Suzuki-Miyaura couplings of heteroaromatic compounds employing low catalyst loadings.
Chemistry 12 , 5142, (2006) The use of second-generation [(NHC)Pd(R-allyl)Cl] complexes for Suzuki-Miyaura and Buchwald-Hartwig cross-coupling reactions involving heteroaromatic halides at room temperature is reported. The first examples of room temperature Suzuki-Miyaura cross-coupling... |