三氯化钌
三氯化钌结构式
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常用名 | 三氯化钌 | 英文名 | ruthenium chloride |
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| CAS号 | 10049-08-8 | 分子量 | 207.429 | |
| 密度 | 3.11 | 沸点 | N/A | |
| 分子式 | Cl3Ru | 熔点 | 500ºC | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS05 |
信号词 | Danger |
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Interaction of ferrocene appended Ru(II), Rh(III) and Ir(III) dipyrrinato complexes with DNA/protein, molecular docking and antitumor activity.
Eur. J. Med. Chem. 84 , 17-29, (2014) Efficacy of the ferrocene appended piano-stool dipyrrinato complexes [(η(6)-C6H6)RuCl(fcdpm)] (1), [(η(6)-C10H14)RuCl(fcdpm)] (2), [(η(6)-C12H18)RuCl(fcdpm)] (3) [(η(5)-C5Me5)RhCl(fcdpm)] (4) and [(η(5)-C5Me5)IrCl(fcdpm)] (5) [fcdpm = 5-ferrocenyldipyrromethe... |
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Surface functionalisation of carbon for low cost fabrication of highly stable electrochemical DNA sensors.
Biosens. Bioelectron. 71 , 25-9, (2015) An alternative strategy for surface tethering of DNA probes, where highly reactive glassy carbon (GC) substrates are prepared via electrochemical hydrogenation and electrochemical/chemical chlorination is reported. Thiolated DNA probes and alkanethiols were s... |
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Curcumin-induced heme oxygenase-1 expression prevents H2O2-induced cell death in wild type and heme oxygenase-2 knockout adipose-derived mesenchymal stem cells.
Int. J. Mol. Sci. 15(10) , 17974-99, (2014) Mesenchymal stem cell (MSC) administration is a promising adjuvant therapy to treat tissue injury. However, MSC survival after administration is often hampered by oxidative stress at the site of injury. Heme oxygenase (HO) generates the cytoprotective effecto... |
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Enhancing the methanol tolerance of platinum nanoparticles for the cathode reaction of direct methanol fuel cells through a geometric design.
Sci. Rep. 5 , 16219, (2015) Mastery over the structure of nanoparticles might be an effective way to enhance their performance for a given application. Herein we demonstrate the design of cage-bell nanostructures to enhance the methanol tolerance of platinum (Pt) nanoparticles while rem... |
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CO Induces Nrf2-Dependent Heme Oxygenase-1 Transcription by Cooperating with Sp1 and c-Jun in Rat Brain Astrocytes.
Mol. Neurobiol. 52 , 277-92, (2015) Upregulation of heme oxygenase 1 (HO-1) by carbon monoxide (CO) delivered by CO-releasing molecules (CORMs) may be utilized as a therapeutic intervention for neurodegenerative diseases. This study was to delineate the two putative anti-oxidant response elemen... |
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Electrochemical electron paramagnetic resonance utilizing loop gap resonators and micro-electrochemical cells.
Phys. Chem. Chem. Phys. 17 , 23438-47, (2015) A miniaturised electrochemical cell design for Electron Paramagnetic Resonance (EPR) studies is reported. The cell incorporates a Loop Gap Resonator (LGR) for EPR investigation of electrochemically generated radicals in aqueous (and other large dielectric los... |
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Ru(II) multinuclear metallosupramolecular rack-type architectures of polytopic hydrazone-based ligands: synthesis, structural features, absorption spectra, redox behavior, and near-infrared luminescence.
Chemistry 16(19) , 5645-60, (2010) A novel class of polytopic hydrazone-based ligands was synthesized. They gave heteroleptic Ru(II) polynuclear rack-like complexes of formula [Ru(n)terpy(n)(bridging molecular strand)](2n+) (terpy=2,2':6',2''-terpyridine). The new rack-like systems can be view... |
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Complete sets of monosubstituted cyclomaltohexaoses (α-cyclodextrins) as precursors for further synthesis.
Carbohydr. Res. 346(15) , 2374-9, (2011) Alkylation of cyclomaltohexaose (α-cyclodextrin, α-CD) with allyl or cinnamyl bromide, followed by peracetylation of remaining hydroxyl groups and separation of isomers, resulted in the set of peracetylated 2(I)-O-, 3(I)-O- and 6(I)-O-alkylated α-CDs in up to... |
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Ruthenium(III) chloride complex with a tridentate bis(arylimino)pyridine ligand: synthesis, spectra, X-ray structure, 9-ethylguanine binding pattern, and in vitro cytotoxicity.
Inorg. Chem. 47(15) , 6964-73, (2008) The synthetic, spectroscopic, structural, and biological studies of a bis(arylimino)pyridine Ru(III) chloride compound containing the ligand, 2,6-bis(2,4,6-trimethylphenyliminomethyl)pyridine are reported. The bis(arylimino)pyridine ligand, with three donor n... |
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Iodine(V)/ruthenium(III)-cocatalyzed oxidations: a highly efficient tandem catalytic system for the oxidation of alcohols and hydrocarbons with oxone.
Chemistry 15(42) , 11091-4, (2009)
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