二叔丁基氯化膦
二叔丁基氯化膦结构式
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常用名 | 二叔丁基氯化膦 | 英文名 | Di-tert-butylchlorophosphane |
|---|---|---|---|---|
| CAS号 | 13716-10-4 | 分子量 | 180.655 | |
| 密度 | 0.951 g/mL at 25 °C(lit.) | 沸点 | 191.6±0.0 °C at 760 mmHg | |
| 分子式 | C8H18ClP | 熔点 | 2-3°C | |
| MSDS | 中文版 美版 | 闪点 | 61.1±0.0 °C | |
| 符号 |
GHS05 |
信号词 | Danger |
|
Synthesis and characterization of R2PN=P(iBuNCH2CH2)3N: a new bulky electron-rich phosphine for efficient Pd-assisted Suzuki-Miyaura cross-coupling reactions.
J. Org. Chem. 72 , 2816, (2007) Pro-azaphosphatrane 1a [P(iBuNCH2CH2)3N] reacts with iodine under mild conditions to give [IP(iBuNCH2CH2)3N]I in excellent yield, which on subsequent reaction with ammonia followed by deprotonation with KOtBu provided HN=P(iBuNCH2CH2)3N (3a) in quantitative y... |
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