四丙基高钌酸铵
四丙基高钌酸铵结构式
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常用名 | 四丙基高钌酸铵 | 英文名 | Tetrapropylammonium perruthenate |
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| CAS号 | 114615-82-6 | 分子量 | 351.425 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C12H28NO4Ru | 熔点 | 160ºC | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS03, GHS07 |
信号词 | Danger |
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Oxidation of hydroxyl-substituted organotrifluoroborates.
J. Am. Chem. Soc. 128 , 9634, (2006) Potassium- and tetra-n-butylammonium organotrifluoroborates containing hydroxyl groups have been prepared and oxidized using several common oxidants. Aryl-, alkenyl-, and alkyltrifluoroborates containing both primary and secondary hydroxyl groups were oxidize... |
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A double donor-activated ruthenium(VII) catalyst: synthesis of enantiomerically pure THF-diols.
Angew. Chem. Int. Ed. Engl. 49(9) , 1587-90, (2010)
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Single-flask synthesis of N-acylated indoles by catalytic dehydrogenative coupling with primary alcohols.
Org. Lett. 11(7) , 1651-4, (2009) Indoles and alcohols can be coupled in a dehydrogenative process catalyzed by tetrapropylammonium perruthenate. This efficient approach to indolylamides proceeds in a single flask under mild conditions. By employing substituted indoles and alkyl, branched, or... |
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Tetrapropylammonium perruthenate as a mild and efficient oxidant for sensitive steroidal alcohols.
Steroids 58(5) , 205-8, (1993) Tetrapropylammonium perruthenate N-methylmorpholine N-oxide oxidation of steroidal alcohols is described. The reagent combination is mild and gave good yields of the corresponding ketones. Although the oxidation can generate ketones from 3-, 11-, 15-, 17-, an... |
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The grounds for the activity of TPAP in oxidation catalysis in supercritical carbon dioxide when confined in hybrid fluorinated silica matrices.
Phys. Chem. Chem. Phys. 10(15) , 2026-32, (2008) Fluorinated organo-silica gels doped with tetra-n-propylammonium perruthenate (TPAP) are excellent catalysts for the aerobic oxidative dehydrogenation of alcohols in supercritical CO2 (scCO2). Their activity and stability are subtly dictated by structure, dep... |
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Synthesis , 639, (1994)
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Aldrichimica Acta 23 , 13, (1990)
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Synthesis 7 , 639-666, (1994)
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Synlett , 948, (2006)
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Tetrahedron Lett. 45 , 303-308, (2004)
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