1,3-双(2,6-二异丙苯基)氯化咪唑鎓
1,3-双(2,6-二异丙苯基)氯化咪唑鎓结构式
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常用名 | 1,3-双(2,6-二异丙苯基)氯化咪唑鎓 | 英文名 | 1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE |
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| CAS号 | 258278-25-0 | 分子量 | 427.065 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C27H39ClN2 | 熔点 | 289-293ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Palladium-(N-heterocyclic carbene) hydrogenation catalysts.
Angew. Chem. Int. Ed. Engl. 44 , 2026, (2005)
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NHC-catalyzed ring expansion of oxacycloalkane-2-carboxaldehydes: a versatile synthesis of lactones.
Org. Lett. 11 , 891, (2009) Imidazolinium-derived carbenes catalyze the ring-expansion lactonization of oxacycloalkane-2-carboxaldehydes. A variety of functionalized five-, six-, and seven-membered lactones can be formed efficiently under mild reaction conditions. The success of this ne... |
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Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions.
J. Org. Chem. 4 , 2079, (2002) [reaction: see text] Catalyst formed from N,N-bis(2,6-diisopropylphenyl)dihydroimidazolium chloride and palladium(II) acetate (2 mol %) was used, without added base, to efficiently produce Heck coupled products with olefins and aryl diazonium tetrafluoroborat... |
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Synlett , 366, (2006)
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