二氟氯乙酸乙酯
二氟氯乙酸乙酯结构式
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常用名 | 二氟氯乙酸乙酯 | 英文名 | Ethyl chloro(difluoro)acetate |
|---|---|---|---|---|
| CAS号 | 383-62-0 | 分子量 | 158.531 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 93.8±35.0 °C at 760 mmHg | |
| 分子式 | C4H5ClF2O2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 28.9±15.1 °C | |
| 符号 |
GHS02, GHS05 |
信号词 | Danger |
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Pathway for the stereocontrolled Z and E production of alpha,alpha-difluorine-substituted phenyl butenoates.
J. Org. Chem. 71(22) , 8618-21, (2006) An efficient preparation of pure ethyl Z- and E-alpha,alpha-difluoro-4-phenyl-3-butenoate 1a and 1b together with the corresponding acids 2a and 2b is described. The procedures involve stereocontrolled additions of *CF2CO2Et to phenylacetylene or beta-bromost... |
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Synthesis of 3-gem-difluoro-2-ethoxy allylic alcohols from ethyl chlorodifluoroacetate. Bégué J-P, et al.
Tetrahedron Lett. 35(3) , 6097-6100, (1994)
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A theoretical investigation on the kinetics and reactivity of the gas-phase reactions of ethyl chlorodifluoroacetate with OH radical and Cl atom at 298 K. Mishra BK, et al.
Struct. Chem. 25(2) , 463-470, (2014)
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Fluorine-containing organozinc reagents. IV.: Reformatskii-type reactions of chlorodifluoroacet1c acid derivatives. Lang RW and Schaub B.
Tetrahedron Lett. 29(24) , 2943-46, (1988)
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