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异丁醛

一般危化品
异丁醛结构式
异丁醛结构式
常用名 异丁醛 英文名 Isobutyraldehyde
CAS号 78-84-2 分子量 72.106
密度 0.8±0.1 g/cm3 沸点 67.1±8.0 °C at 760 mmHg
分子式 C4H8O 熔点 −65 °C(lit.)
MSDS 中文版 美版 闪点 -18.9±0.0 °C
符号 GHS02 GHS07
GHS02, GHS07
信号词 Danger

Comparison of Aroma-Active Volatiles in Oolong Tea Infusions Using GC-Olfactometry, GC-FPD, and GC-MS.

J. Agric. Food Chem. 63 , 7499-510, (2015)

The aroma profile of oolong tea infusions (Dongdingwulong, DDWL; Tieguanyin, TGY; Dahongpao, DHP) were investigated in this study. Gas chromatography-olfactometry (GC-O) with the method of aroma intensity (AI) was employed to investigate the aroma-active comp...

Orientation to determine quality attributes of flavoring excipients containing volatile molecules.

J. Pharm. Biomed. Anal. 110 , 20-6, (2015)

Pharmaceutical excipients containing volatile odor-active molecules can be used in pharmaceutical development to increase patients' compliance. However, capturing the molecular composition of these odor-active substances is challenging. Therefore, guidance fo...

Alkaline comet assay in liver and stomach, and micronucleus assay in bone marrow, from rats treated with 2-acetylaminofluorene, azidothymidine, cisplatin, or isobutyraldehyde.

Mutat. Res. Genet. Toxicol. Environ. Mutagen. 786-788 , 77-86, (2015)

As part of the Japanese Center for the Validation of Alternative Methods (JaCVAM) initiative international validation study of the in vivo rat alkaline comet assay (comet assay), we examined the ability of the assay to determine the genotoxicity of 2-acetylam...

Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere.

Phys. Chem. Chem. Phys. 17 , 17914-26, (2015)

Methacryloyl peroxynitrate (MPAN), the acyl peroxynitrate of methacrolein, has been suggested to be an important secondary organic aerosol (SOA) precursor from isoprene oxidation. Yet, the mechanism by which MPAN produces SOA through reaction with the hydroxy...

Analysis of volatile organic compounds liberated and metabolised by human umbilical vein endothelial cells (HUVEC) in vitro.

Cell Biochem. Biophys. 71(1) , 323-9, (2015)

Gas chromatography with mass spectrometric detection combined with head-space needle trap extraction as the pre-concentration technique was applied to identify and quantify volatile organic compounds released or metabolised by human umbilical vein endothelial...

Direct photosynthetic recycling of carbon dioxide to isobutyraldehyde.

Nat. Biotechnol. 27(12) , 1177-80, (2009)

Global climate change has stimulated efforts to reduce CO(2) emissions. One approach to addressing this problem is to recycle CO(2) directly into fuels or chemicals using photosynthesis. Here we genetically engineered Synechococcus elongatus PCC7942 to produc...

Chiral picolylamines for Michael and aldol reactions: probing substrate boundaries.

Org. Biomol. Chem. 10(46) , 9287-94, (2012)

Here we report on inroads concerning increased substrate breadth via the picolylamine organocatalyst template, a vicinal chiral diamine based on a pyridine-primary amine motif. The addition of cyclohexanone to β-nitrostyrene has many catalyst solutions, but c...

Identification of distinctive volatile compounds in fish sauce.

J. Agric. Food Chem. 50(19) , 5412-6, (2002)

To make clear the distinctive odorants of fish sauce, addition tests were carried out with respect to deodorized fish sauce samples. Volatiles from the headspace gas of nontreated fish sauce and deodorized fish sauce were characterized by gas chromatography-o...

Quantum mechanical predictions of the stereoselectivities of proline-catalyzed asymmetric intermolecular aldol reactions.

J. Am. Chem. Soc. 125(9) , 2475-9, (2003)

Quantum mechanical calculations were employed to predict the ratio of four stereoisomeric products expected from two complex reactions involving the aldol reactions of cyclohexanone with benzaldehyde or with isobutyraldehyde catalyzed by (S)-proline. Experime...

Characterization of Nutty Flavor in Cheddar Cheese

J. Dairy Sci. 87(7) , 1999-2010, (2004)

The objectives of this study were to determine the volatile components responsible for the sensory perception of nutty flavor in Cheddar cheese. Cheddar cheeses with and without nutty flavors were selected by descriptive sensory analysis. Volatile aroma compo...