双三苯基磷二氯化钯
双三苯基磷二氯化钯结构式
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常用名 | 双三苯基磷二氯化钯 | 英文名 | Bis(triphenylphosphine) Palladium (II) Chloride |
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| CAS号 | 13965-03-2 | 分子量 | 701.897 | |
| 密度 | N/A | 沸点 | 360ºC at 760 mmHg | |
| 分子式 | C36H30Cl2P2Pd | 熔点 | 260°C | |
| MSDS | 中文版 美版 | 闪点 | 181.7ºC | |
| 符号 |
GHS08 |
信号词 | Warning |
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Expedient synthesis of tetrasubstituted pyrroles via a copper-catalyzed cascade inter-/intramolecular cyclization of 1,3-enynes carry a nitro group with amines.
Org. Biomol. Chem. 13(9) , 2786-92, (2015) Various tetrasubstituted pyrroles/pyrazoles have been prepared from nitro-substituted 1,3-enynes with aromatic amines/hydrazines via a copper-catalyzed cascade aza-Michael addition, cyclization and aromatization at room temperature. This protocol is also effe... |
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Color Tuning of the Aggregation-Induced Emission of Maleimide Dyes by Molecular Design and Morphology Control.
Chemistry 21 , 12105-11, (2015) Aggregation-induced emission (AIE)-active maleimide dyes, namely, 2-p-toluidino-N-p-tolylmaleimide, 3-phenyl-2-toluidino-N-p-tolylmaleimide, 2-p-thiocresyl-3-p-toluidino-N-p-tolylmaleimide, and 2,3-dithiocresyl-N-arylmaleimides, were synthesized by facile syn... |
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Imidazolium salts with varying anions as charge carriers for detection of neutral bis(triphenylphosphine)palladium(II) dichloride in electrospray ionization mass spectrometry.
Rapid Commun. Mass Spectrom. 27(17) , 1954-60, (2013) While electrospray ionization is a popular technique for mass analysis, without a charged species it is ineffective. This coupled with solvent restrictions hinders the analysis of organometallic complexes. Detecting neutral species whose solubility is limited... |
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Evaluation of functionalized silica's for the adsorptive recovery of homogenous catalysts through interaction with the metal centre.
J. Chromatogr. A. 1142(1) , 32-8, (2007) The goal of this paper is the evaluation of functionalized silica's for the recovery of homogeneous catalysts by adsorption via its metal centre. As model catalysts, we selected bis(triphenylphosphine)cobalt(II)dichloride (CoCl(2)(PPh(3))(2)), bis(triphenylph... |
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Single-isomer tetrasubstituted olefins from regioselective and stereospecific palladium-catalyzed coupling of beta-chloro-alpha-iodo-alpha,beta-unsaturated esters.
J. Org. Chem. 71(9) , 3615-3618, (2006) The efficient regioselective and stereospecific synthesis of tetrasubstituted olefins using a mild and convenient method is disclosed. 2-Alkynyl esters are selectively converted to E-beta-chloro-alpha-iodo-alpha,beta-unsaturated esters by exposure to Bu4NI in... |
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Heck reaction catalyzed by phospha-palladacycles in non-aqueous ionic liquids. Herrmann WA and Böhm VPW.
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Tetrahedron Lett. 45 , 4823-4826, (2004)
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Tetrahedron 62 , 9548, (2006)
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A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines. Sonogashira K, et al.
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