硼氢化锂
一般危化品
硼氢化锂结构式
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常用名 | 硼氢化锂 | 英文名 | lithium borohydride |
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| CAS号 | 16949-15-8 | 分子量 | 21.784 | |
| 密度 | 0.896 g/mL at 25 °C | 沸点 | 66°C/760mmHg | |
| 分子式 | BH3Li | 熔点 | 280 °C | |
| MSDS | 中文版 美版 | 闪点 | −1 °F | |
| 符号 |
GHS02, GHS05, GHS06 |
信号词 | Danger |
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Cytotoxicity of thiazolidinedione-, oxazolidinedione- and pyrrolidinedione-ring containing compounds in HepG2 cells.
Toxicol. In Vitro 29 , 1887-96, (2015) Liver damage occurred in some patients who took troglitazone (TGZ) for type II diabetes. The 2,4-thiazolidinedione (TZD) ring in TGZ's structure has been implicated in its hepatotoxicity. To further examine the potential role of a TZD ring in toxicity we used... |
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Destabilisation of complex hydrides through size effects.
Nanoscale 2(12) , 2587-90, (2010) Nanoparticles of NaAlH4, LiAlH4 and LiBH4 were prepared by encapsulating their respective hydrides within carbon nanotubes by a wet chemical approach. The resulting confinement had a profound effect on the overall hydrogen storage properties of these hydrides... |
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A new synthesis of Rink's polymer, 4-(2',4'-dimethoxyphenylhydroxymethyl)phenoxymethylpolystyrene .
Int. J. Pept. Protein Res. 43(1) , 29-30, (1994) For solid-phase peptide synthesis, 2,4-dimethoxy-4'-hydroxbenzhydrol linker was prepared via lithium borohydride reduction of 2,4-dimethoxy-4'-hydroxybenozophenone. The potassium salt of the linker was coupled to chloromethylpolystyrene. This method proved to... |
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Experimental and theoretical screening of nanoscale oxide reactivity with LiBH4.
Nanotechnology 20(20) , 204024, (2009) Experimentation, thermodynamic modeling, and atomic modeling were combined to screen the reactivity of SiO2, Al2O3, and ZrO2 nanoscale oxides with LiBH4. Equilibrium thermodynamic modeling showed that the reactions of oxides with LiBH4 could lead to formation... |
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A radioluminescence study of spectral and dose characteristics of common luminophors.
Radiat. Prot. Dosimetry 100(1-4) , 403-6, (2002) Many synthetic materials are used as thermoluminescence dosemeters for the measurement of the absorbed dose from ionising radiation sources. A part of the absorbed energy leads to a prompt luminescence (radioluminescence, abbreviated RL) which dose behaviour ... |
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In situ X-ray Raman spectroscopy of LiBH4.
Phys. Chem. Chem. Phys. 14(16) , 5581-7, (2012) X-Ray Raman Spectroscopy (XRS) is used to study the electronic properties of bulk lithium borohydride (LiBH(4)) and LiBH(4) in porous carbon nano-composites (LiBH(4)/C) during dehydrogenation. The lithium (Li), boron (B) and carbon (C) K-edges are studied and... |
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Remarkably stable tetrahedral intermediates: carbinols from nucleophilic additions to N-acylpyrroles.
Angew. Chem. Int. Ed. Engl. 41(17) , 3188-91, (2002)
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Stereoselective diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based polycyclic derivatives.
J. Comb. Chem. 6(1) , 54-64, (2004) A diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based tricyclic derivatives has been achieved from enantiomerically pure, natural product-like bicyclic scaffold. The solution synthesis of enantiopure bicyclic scaffold was develo... |
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Novel catalytic effects of fullerene for LiBH4 hydrogen uptake and release.
Nanotechnology 20(20) , 204022, (2009) The addition of catalysts to complex hydrides is aimed at enhancing the hydrogen absorption desorption properties. Here we show that the addition of carbon nanostructure C60 to LiBH4 has a remarkable catalytic effect, enhancing the uptake and release of hydro... |
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Size effects on the hydrogen storage properties of nanoscaffolded Li3BN2H8.
Nanotechnology 20(20) , 204002, (2009) The use of Li3BN2H8 complex hydride as a practical hydrogen storage material is limited by its high desorption temperature and poor reversibility. While certain catalysts have been shown to decrease the dehydrogenation temperature, no significant improvement ... |