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18779-08-3生产厂家

18779-08-3价格

18779-08-3

18779-08-3结构式
18779-08-3结构式

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中文名 乙酸镥
英文名 lutetium acetate
中文别名 醋酸镥
英文别名 EINECS 242-566-3
LUTETIUM(III) ACETATE HYDRATE
aceticacid,lutetium(3++)salt
LUTECIUM ACETATE
lutetium(3+) acetate
MFCD00150119
Triacetic acid lutetium salt
LUTETIUM (III) ACETATE
沸点 117.1ºC at 760 mmHg
分子式 C6H11LuO7
分子量 370.11400
闪点 40ºC
精确质量 369.99100
PSA 88.13000
外观性状 白色结晶
储存条件 室温,密封
稳定性

与1,10菲咯啉作用得到热稳定络合物

计算化学

1、 氢键供体数量:0

2、 氢键受体数量:6

3、 可旋转化学键数量:0

4、 拓扑分子极性表面积(TPSA):120

5、 重原子数量:13

6、 表面电荷:0

7、 复杂度:25.5

8、 同位素原子数量:0

9、 确定原子立构中心数量:0

10、 不确定原子立构中心数量:0

11、 确定化学键立构中心数量:0

12、 不确定化学键立构中心数量:0

13、 共价键单元数量:4

更多

1. 性状:无色固体,溶于水。具吸湿性。

2. 密度(g/mL,25/4℃):不确定

3. 相对蒸汽密度(g/mL,空气=1):不确定

4. 熔点(ºC):277~280

5. 沸点(ºC,常压):不确定

6. 沸点(ºC, 5.2kPa):不确定

7. 折射率:不确定

8. 闪点(ºC):不确定

9. 比旋光度(º):不确定

10. 自燃点或引燃温度(ºC):不确定

11. 蒸气压(kPa,25ºC):不确定

12. 饱和蒸气压(kPa,60ºC):不确定

13. 燃烧热(KJ/mol):不确定

14. 临界温度(ºC):不确定

15. 临界压力(KPa):不确定

16. 油水(辛醇/水)分配系数的对数值:不确定

17. 爆炸上限(%,V/V):不确定

18. 爆炸下限(%,V/V):不确定

19. 溶解性:不确定


Section 1: Product Identification
Chemical Name:Lutetium (III) acetate hydrate(99.9%-Lu) (REO)
CAS Registry Number:18779-08-3
Formula:Lu(OOCCH3)3.XH2O
EINECS Number:242-566-3
Chemical Family:metal acetate salt
Synonym:Acetic acid, lutetium(+3) salt, hydrate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound18779-08-3100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a sealed container. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white xtl.
Molecular Weight:352.11
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable solid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents and active metals
Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
危害码 (欧洲) Xi
风险声明 (欧洲) R36/37/38:Irritating to eyes, respiratory system and skin .
安全声明 (欧洲) S24/25

氧化镥(Ⅲ)10g加至500mL 50%醋酸水溶液中,用蒸气浴加热使溶。有时氧化镥(Ⅲ)需用蒸气浴加热一周,才能完全溶解。若加热一周后仍有少量氧化镥(Ⅲ)未能溶解,则需过滤。将清亮溶液放在75℃水浴上加热以蒸去大部分溶剂。冷却,晶体析出,滤集晶体,将其移入玻璃皿中,放在置有粒状氢氧化钠及高氯酸镁的真空保干器中进行干燥,所得产物为水合物。

将水合物晶体置于真空干燥枪(阿布得哈顿干燥器)中,于75℃减压(抽真空)干燥至恒重,得到无水醋酸镥(Ⅲ)。