| 中文名 | 章鱼碱 |
|---|---|
| 英文名 | D-octopine |
| 中文别名 | (+)-真蛸碱 |
| 英文别名 |
N2-(1-CARBOXYETHYL)-L-ARGININE
(R),(S)-octopine N2-(1-Carboxyethyl)-L-arginine,N2-([R]-1-Carboxyethyl)-L-arginine D-(+)-Octopine N2-(1-Carboxyethyl)-L-arginine N2-([R]-1-Carboxyethyl)-L-arginine (+)-OCTOPINE N2-[(R)-1-CARBOXYETHYL]-L-ARGININE |
| 密度 | 1.45g/cm3 |
|---|---|
| 沸点 | 526.4ºC at 760mmHg |
| 熔点 | 283-284ºC(lit.) |
| 分子式 | C9H18N4O4 |
| 分子量 | 246.26400 |
| 闪点 | 272.1ºC |
| 精确质量 | 246.13300 |
| PSA | 148.53000 |
| LogP | 0.34740 |
| 折射率 | 1.592 |
| 储存条件 | 密封、在 -20ºC下保存 |
| 稳定性 | 常温常压下稳定 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）：-3.7 2、 氢键供体数量：5 3、 氢键受体数量：8 4、 可旋转化学键数量：8 5、 互变异构体数量：2 6、 拓扑分子极性表面积（TPSA）：151 7、 重原子数量：17 8、 表面电荷：0 9、 复杂度：301 10、同位素原子数量：0 11、确定原子立构中心数量：1 12、不确定原子立构中心数量：1 13、确定化学键立构中心数量：0 14、不确定化学键立构中心数量：0 15、共价键单元数量：1 |
| 更多 | 1. 性状：白色至茶色粉末 2. 密度（g/mL, 20 ℃ ）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：283-284 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,KPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（Pa,20ºC）：未确定 12. 饱和蒸气压（KPa,20ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. The toxicological properties of this material have not been fully investigated. Skin: May cause skin irritation. The toxicological properties of this material have not been fully investigated. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 34522-32-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 283.00 - 284.00 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H18N4O4 Molecular Weight: 246.27 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, excess heat, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 34522-32-2 unlisted. LD50/LC50: Not available. Carcinogenicity: (+)-Octopine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 34522-32-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 34522-32-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 34522-32-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 安全声明 (欧洲) | S24/25 |
|---|---|
| 海关编码 | 2925290090 |
|
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34522-32-2 |
| 文献：Journal of Biochemistry (Tokyo, Japan), , vol. 25, p. 283 Chem. Zentralbl., , vol. 109, # I p. 1133 Journal of Organic Chemistry, , vol. 11, p. 375 |
|
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34522-32-2 |
| 文献：Journal of the American Chemical Society, , vol. 79, p. 652,657 Anm. 32 |
|
~%
34522-32-2 |
| 文献：Journal of Biological Chemistry, , vol. 127, p. 573 |
|
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34522-32-2 |
| 文献：Bulletin of the Chemical Society of Japan, , vol. 55, # 1 p. 261 - 265 |
|
~%
34522-32-2 |
| 文献：Journal of the American Chemical Society, , vol. 79, p. 652,657 Anm. 32 |
| 上游产品 7 | |
|---|---|
| 下游产品 6 | |
| 海关编码 | 2925290090 |
|---|---|
| 中文概述 | 2925290090 其他亚胺及其衍生物，以及它们的盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
