2,2,2-Trichloroethoxysulfonamide

2,2,2-Trichloroethoxysulfonamide Structure
2,2,2-Trichloroethoxysulfonamide structure
Common Name 2,2,2-Trichloroethoxysulfonamide
CAS Number 69226-51-3 Molecular Weight 228.48200
Density 1.801g/cm3 Boiling Point 288.7ºC at 760 mmHg
Molecular Formula C2H4Cl3NO3S Melting Point 56 °C
MSDS Chinese USA Flash Point 128.4ºC

Catalytic intermolecular amination of C-H bonds: method development and mechanistic insights.

J. Am. Chem. Soc. 129 , 562, (2007)

Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiome...