1,3-Dioxolane
1,3-Dioxolane structure
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Common Name | 1,3-Dioxolane | ||
|---|---|---|---|---|
| CAS Number | 646-06-0 | Molecular Weight | 74.078 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 75.6±0.0 °C at 760 mmHg | |
| Molecular Formula | C3H6O2 | Melting Point | −95 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 1.7±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
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Nanoporous Cathodes for High-Energy Li-S Batteries from Gyroid Block Copolymer Templates.
ACS Nano 9 , 6147-57, (2015) This study reports on a facile approach to the fabrication of nanoporous carbon cathodes for lithium sulfur batteries using gyroid carbon replicas based on use of polystyrene-poly-4-vinylpyridine (PS-P4VP) block copolymers as sacrificial templates. The free-s... |
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Synthesis of three-dimensionally interconnected sulfur-rich polymers for cathode materials of high-rate lithium-sulfur batteries.
Nat. Commun. 6 , 7278, (2015) Elemental sulfur is one of the most attractive cathode active materials in lithium batteries because of its high theoretical specific capacity. Despite the positive aspect, lithium-sulfur batteries have suffered from severe capacity fading and limited rate ca... |
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Reactivity of fullerene epoxide: preparation of fullerene-fused thiirane, tetrahydrothiazolidin-2-one, and 1,3-dioxolane.
J. Org. Chem. 73(7) , 2518-26, (2008) The epoxide moiety in the fullerene-mixed peroxide C60(O)(OOtBu)4 1 reacts readily with aryl isocyanates ArNCS (Ar = Ph, Naph) to form both the thiirane derivative C60(S)(OOtBu)4 and fullerene-fused tetrahydrothiazolidin-2-one. The reaction of 1 with trimethy... |
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High rate and stable cycling of lithium metal anode.
Nat. Commun. 6 , 6362, (2015) Lithium metal is an ideal battery anode. However, dendrite growth and limited Coulombic efficiency during cycling have prevented its practical application in rechargeable batteries. Herein, we report that the use of highly concentrated electrolytes composed o... |
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The first de novo-designed antagonists of the human NK(2) receptor.
J. Med. Chem. 48(18) , 5655-8, (2005) The de novo molecular design program SPROUT has been used in conjunction with a molecular model to produce a molecular template for a new class of NK(2) receptor antagonist. An efficient, stereocontrolled synthesis of a small series of molecules, designed to ... |
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1,3-Dioxolane-based ligands incorporating a lactam or imide moiety: structure-affinity/activity relationship at alpha1-adrenoceptor subtypes and at 5-HT1A receptors.
Eur. J. Med. Chem. 45(9) , 3740-51, (2010) A series of 1,3-dioxolane-based compounds incorporating a lactam (2-4) or imide (5-7) moiety was synthesized and the pharmacological profile at alpha(1)-adrenoceptor subtypes and 5-HT(1A) receptor was assessed through binding and functional experiments. Start... |
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One-step synthesis of 2-alkyl-dioxolanes from ethylene glycol and syngas.
ChemSusChem 2(10) , 941-3, (2009)
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Evaluation of a bromine-76-labeled progestin 16alpha,17alpha-dioxolane for breast tumor imaging and radiotherapy: in vivo biodistribution and metabolic stability studies.
Nucl. Med. Biol. 35(6) , 655-63, (2008) Progesterone receptors (PRs) are present in many breast tumors, and their levels are increased by certain endocrine therapies. They can be used as targets for diagnostic imaging and radiotherapy.16alpha,17alpha-[(R)-1'-alpha-(5-[(76)Br]Bromofurylmethylidene)d... |
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Biochemical studies on the mechanism of human immunodeficiency virus type 1 reverse transcriptase resistance to 1-(beta-D-dioxolane)thymine triphosphate.
Antimicrob. Agents Chemother. 51(6) , 2078-84, (2007) A large panel of drug-resistant mutants of human immunodeficiency virus type 1 reverse transcriptase (RT) was used to study the mechanisms of resistance to 1-(beta-d-dioxolane)thymine triphosphate (DOT-TP) and other nucleotide analogs. RT containing thymidine... |
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Synthesis of fused-β-lactams through selective gold-catalyzed oxycyclization of dioxolane-tethered enynes.
J. Org. Chem. 78(18) , 8956-65, (2013) The gold-catalyzed preparation of 2-azetidinone-fused oxacycles was accomplished from β-lactam-linked enynes through heterocyclization reaction taking advantage of the acetonide pendant group. While the synthesis of fused tetrahydrofuran-β-lactams from 1,3-en... |