Tris(pentafluorophenyl)phosphine
Tris(pentafluorophenyl)phosphine structure
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Common Name | Tris(pentafluorophenyl)phosphine | ||
|---|---|---|---|---|
| CAS Number | 1259-35-4 | Molecular Weight | 532.15 | |
| Density | N/A | Boiling Point | 343.4±42.0 °C at 760 mmHg | |
| Molecular Formula | C18F15P | Melting Point | 108-110 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 161.5±27.9 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species.
J. Am. Chem. Soc. 127(18) , 6573-82, (2005) Porphyrin-manganese(V)-oxo and porphyrin-manganese(IV)-oxo species were produced in organic solvents by laser flash photolysis (LFP) of the corresponding porphyrin-manganese(III) perchlorate and chlorate complexes, respectively, permitting direct kinetic stud... |
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Structure of tris(pentafluorophenyl)phosphine.
Acta Crystallogr. C 45 ( Pt 11) , 1743-5, (1989) C18F15P, Mr = 532.1, monoclinic, P2(1)/c, a = 7.194 (2), b = 17.930 (4), c = 13.834 (2) A, beta = 94.29 (2) degrees, V = 1779 A3, Z = 4, Dm = 2.00, Dx = 1.99 g cm-3, lambda(Mo K alpha) = 0.71073 A, mu = 3.3 cm-1, F(000) = 1032, T approximately equal to 296 K,... |
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Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates.
Eur. J. Mass Spectrom. (Chichester, Eng.) 16(3) , 407-14, (2010) Functional models of the Compound I intermediate of monooxygenase heme enzymes, namely [(TPFPP)(*+)Fe(IV)=O](+) and [(TPFPP)Mn(V)=O](+) (TPFPP = meso-tetrakis (pentafluorophenyl)porphyrinato dianion), are obtained as bare species by electrospray ionization fr... |