Methyldifluor(fluorsulfonyl)acetat

Methyldifluor(fluorsulfonyl)acetat Structure
Methyldifluor(fluorsulfonyl)acetat structure
Common Name Methyldifluor(fluorsulfonyl)acetat
CAS Number 680-15-9 Molecular Weight 192.114
Density 1.6±0.1 g/cm3 Boiling Point 150.0±40.0 °C at 760 mmHg
Molecular Formula C3H3F3O4S Melting Point N/A
MSDS Chinese USA Flash Point 44.5±27.3 °C
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

Evaluating the thermal vinylcyclopropane rearrangement (VCPR) as a practical method for the synthesis of difluorinated cyclopentenes: experimental and computational studies of rearrangement stereospecificity.

Chemistry 20(44) , 14305-16, (2014)

Vinyl cyclopropane rearrangement (VCPR) has been utilised to synthesise a difluorinated cyclopentene stereospecifically and under mild thermal conditions. Difluorocyclopropanation chemistry afforded ethyl 3-(1'(2'2'-difluoro-3'-phenyl)cyclopropyl) propenoate ...

A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides.

Angew. Chem. Int. Ed. Engl. 50 , 3793, (2011)

J. Chem. Soc. Chem. Commun. , 705, (1989)