(Isopropenyloxy)(trimethyl)silane
(Isopropenyloxy)(trimethyl)silane structure
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Common Name | (Isopropenyloxy)(trimethyl)silane | ||
|---|---|---|---|---|
| CAS Number | 1833-53-0 | Molecular Weight | 130.260 | |
| Density | 0.8±0.1 g/cm3 | Boiling Point | 93.0±8.0 °C at 760 mmHg | |
| Molecular Formula | C6H14OSi | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 7.2±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
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Concise total synthesis and stereochemical revision of (+)-naseseazines A and B: regioselective arylative dimerization of diketopiperazine alkaloids.
J. Am. Chem. Soc. 133 , 14940-14943, (2011) Concise and enantioselective total syntheses of (+)-naseseazines A and B are described. Our regioselective and directed dimerization of diketopiperazines provides their critical C3-C(sp(2)) linkages, an assembly with plausible biogenetic relevance. We revise ... |
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Total synthesis of (+/-)-powelline and (+/-)-buphanidrine.
Org. Lett. 12(6) , 1252-4, (2010) The total synthesis of (+/-)-powelline (13 linear steps in an overall yield of 6%) and (+/-)-buphanidrine (14 linear steps and a 6% overall yield) and has been achieved using a novel approach to the crinane skeleton. An organocatalytic oxidative coupling allo... |
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Organotin triflate as practical catalyst for Michael addition of enol silyl ethers. Sato T, et al.
Tetrahedron 47(47) , 9773-82, (1991)
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