3-Amino-5-bromobenzotrifluoride

3-Amino-5-bromobenzotrifluoride Structure
3-Amino-5-bromobenzotrifluoride structure
Common Name 3-Amino-5-bromobenzotrifluoride
CAS Number 54962-75-3 Molecular Weight 240.020
Density 1.7±0.1 g/cm3 Boiling Point 231.2±40.0 °C at 760 mmHg
Molecular Formula C7H5BrF3N Melting Point N/A
MSDS Chinese USA Flash Point 93.6±27.3 °C
Symbol GHS07
GHS07
Signal Word Warning

Me3(OMe)tBuXPhos: a surrogate ligand for Me4tBuXPhos in palladium-catalyzed C-N and C-O bond-forming reactions.

J. Org. Chem. 77(5) , 2543-7, (2012)

A new biarylphosphine ligand, Me(3)(OMe)tBuXPhos (L3), was designed as a surrogate for Me(4)tBuXPhos (L1). The Me(3)(OMe)tBuXPhos could be prepared in a chromatography-free manner from inexpensive and readily available 2,3,6-trimethylphenol. Comparative studi...