6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl-
![6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl- Structure](https://image.chemsrc.com/caspic/220/529-81-7.png)
6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl- structure
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Common Name | 6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl- | ||
|---|---|---|---|---|
| CAS Number | 529-81-7 | Molecular Weight | 250.33800 | |
| Density | 1.21g/cm3 | Boiling Point | 461ºC at 760mmHg | |
| Molecular Formula | C17H18N2 | Melting Point | 133-136ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 213.5ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Tröger's base-functionalised organic nanoporous polymer for heterogeneous catalysis.
Chem. Commun. (Camb.) 46(6) , 970-2, (2010) An organic nanoporous polymer (BET surface area of 750 m(2) g(-1)) containing bicovalently-bonded Tröger's base as functional moieties in the network was synthesized, characterised, and further applied as a promising heterogeneous catalyst in the addition rea... |
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Intermittent simulated moving bed chromatography: 3. Separation of Tröger's base enantiomers under nonlinear conditions.
J. Chromatogr. A. 1218(52) , 9345-52, (2011) One of the modified simulated moving bed (SMB) processes, the intermittent SMB (I-SMB) process, has been recently analyzed theoretically [1] and its superior performance compared to the conventional SMB process has been demonstrated at a rather low total feed... |
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Tröger's-base-derived infinite co-ordination polymer microparticles.
Small 5(1) , 46-50, (2009)
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Enantioseparation of tetrahydropalmatine and Tröger's base by molecularly imprinted monolith in capillary electrochromatography.
J. Biochem. Biophys. Methods 70(1) , 71-6, (2007) Two chiral compounds, Tröger's base and tetrahydropalmatine, were enantioseparated on the (5S, 11S)-(-)-Tröger's base and l-tetrahydropalmatine imprinted monolithic capillary columns with CEC, respectively. The monoliths were prepared by in situ thermal-initi... |
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Tröger's base. An alternate synthesis and a structural analog with thromboxane A2 synthetase inhibitory activity.
J. Med. Chem. 36(21) , 3202-6, (1993) The synthesis of 2,8-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine (Tröger's base) from p-toluidine and of two Tröger's base analogs from other anilines by reaction with hexamethylenetetramine in trifluoroacetic acid is described. 2,3,6,7-Tetrahydro-... |
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Optically active Ru(II) complexes with a chiral Tröger's base ligand and their interactions with DNA.
J. Inorg. Biochem. 101(7) , 987-96, (2007) Three stereoisomers of a Ru(II) complex bearing a chiral bis-phenanthroline Tröger's base analogue, TBphen2 (1), have been isolated from the reaction of the enantiomerically pure precursor complex Lambda- (or Delta-) cis-[Ru(phen)2(py)2]2+ (phen=1,10-phenanth... |
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The mechanism of Tröger's base formation probed by electrospray ionization mass spectrometry.
J. Org. Chem. 72(11) , 4048-54, (2007) Using direct infusion electrospray ionization mass and tandem mass spectrometric experiments [ESI-MS(/MS)], we have performed on-line monitoring of some reactions used to form Tröger's bases. Key intermediates, either as cationic species or as protonated form... |
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(1)H and (13)C NMR studies of asymmetrically substituted bis- and tris-Tröger's bases.
Magn. Reson. Chem. 43(8) , 665-9, (2005) The (1)H and (13)C NMR spectra of two stereoisomeric bis-Tröger's bases and four stereoisomeric tris-Tröger's bases asymmetrically substituted on the external aromatic rings were recorded and the corresponding signals assigned. The relative configuration of t... |
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Molecular modelling study of DNA-Troeger's bases interactions.
J. Biomol. Struct. Dyn. 12(3) , 637-53, (1994) The two enantiomeric forms: 1R,5R (R) and 1S,5S (S) of the Troeger's base analog, 9,19-methano-9,10,19,20-tetrahydrodiacridino-[b,f]-[1,5]- diazocine which possess a C2 axis of symmetry, are susceptible to interact differently with DNA. This paper reports the... |
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Tröger's Base-based Copolymers with Intrinsic Microporosity for CO2 Separation and Effect of Tröger's Base on Separation Performance. Wang ZG, et al. , 10.1039/C3PY01608K
Polym. Chem. , (2013)
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