3-Phenylpropanal
3-Phenylpropanal structure
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Common Name | 3-Phenylpropanal | ||
|---|---|---|---|---|
| CAS Number | 104-53-0 | Molecular Weight | 134.175 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 217.7±0.0 °C at 760 mmHg | |
| Molecular Formula | C9H10O | Melting Point | -42 °C | |
| MSDS | Chinese USA | Flash Point | 95.0±0.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Well-defined N-heterocyclic carbene silver halides of 1-cyclohexyl-3-arylmethylimidazolylidenes: synthesis, structure and catalysis in A3-reaction of aldehydes, amines and alkynes.
Dalton Trans. 40(9) , 2046-52, (2011) Structurally well-defined N-heterocyclic carbene silver chlorides and bromides supported by 1-cyclohexyl-3-benzylimidazolylidene (CyBn-NHC) or 1-cyclohexyl-3-naphthalen-2-ylmethylimidazolylidene (CyNaph-NHC) were synthesized by reaction of the corresponding i... |
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Rh-catalyzed linear hydroformylation of styrene.
Dalton Trans. 42(1) , 137-42, (2013) Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldehyde. An inversion of regioselectivity can be achieved using strong π-acceptor ligands. Binaphthol-based diphosphite and bis(dipyrrolyl-phosphorodiamidite) liga... |
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Enantioselective -Chlorination of Aldehydes with Recyclable Fluorous (S)-Pyrrolidine-Thiourea Bifunctional Organocatalyst.
Synlett 3(2010) , 433-436, (2010) A novel fluorous (S)-pyrrolidine-thiourea bifunctional organocatalyst is prepared. The catalyst shows good activity and enantioselectivity for direct -chlorination of aldehydes using N-chlorosuccinimide (NCS) as the chlorine source. It can be recovered from t... |
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Total synthesis of (+)-strictifolione.
Org. Lett. 5(11) , 1995-7, (2003) [reaction: see text] The synthesis of (+)-strictifolione was achieved from 3-phenylproprionaldehyde by using enantioselective allyltitanations to control the stereogenic centers at C6, C4', and C6' and a cross-methathesis to control the configuration of the d... |
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The arduous way to the egg: follow the nose.
Angew. Chem. Int. Ed. Engl. 42(39) , 4729-31, (2003)
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In vivo cytokine modulatory effects of cinnamaldehyde, the major constituent of leaf essential oil from Cinnamomum osmophloeum Kaneh.
Phytother Res. 25(10) , 1511-8, (2011) The purpose of this study was to analyse the major compound in the leaf essential oil of Cinnamomum osmophloeum Kaneh. and to examine its in vivo toxicity and cytokine-modulatory effects. The HS-GC/MS and quantitative HPLC analyses showed the concentrations o... |
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Chiral Brønsted acid catalyzed enantioselective synthesis of anti-homopropargyl alcohols via kinetic resolution-aldehyde allenylboration using racemic allenylboronates.
Org. Lett. 15(7) , 1568-71, (2013) A chiral phosphoric acid catalyzed kinetic resolution/allenylboration of racemic allenylboronates with aldehydes is described. Allenylboration of aldehydes with 2.8 equiv of allenylboronate (±)-1 in the presence of 10 mol % of catalyst (R)-2 provided anti-hom... |
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Direct Aerobic , _-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)(2)/4,5-Diazafluorenone Catalyst().
Chem. Sci. 3 , 887-891, (2012) The direct , _-dehydrogenation of aldehydes and ketones represents an efficient alternative to stepwise methods to prepare enal and enone products. Here, we describe a new Pd(TFA)(2)/4,5-diazafluorenone dehydrogenation catalyst that overcomes key limitations ... |
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Enantioselective syntheses of syn- and anti-β-hydroxyallylsilanes via allene hydroboration-aldehyde allylboration reactions.
Org. Lett. 13(8) , 1992-5, (2011) The kinetic hydroboration of allenylsilane 5 with ((d)Ipc)(2)BH at -40 °C provides allylborane 9Z with ≥12:1 selectivity. When the hydroboration is performed at temperatures above -40 °C, 9Z isomerizes to the thermodynamically more stable allylborane 9E with ... |
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Enantioselective henry reactions under dual Lewis acid/amine catalysis using chiral amino alcohol ligands.
Angew. Chem. Int. Ed. Engl. 44(25) , 3881-4, (2005)
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