Ethyl (trimethylsilyl)acetate
Ethyl (trimethylsilyl)acetate structure
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Common Name | Ethyl (trimethylsilyl)acetate | ||
|---|---|---|---|---|
| CAS Number | 4071-88-9 | Molecular Weight | 160.286 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 157.5±0.0 °C at 760 mmHg | |
| Molecular Formula | C7H16O2Si | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 35.0±0.0 °C | |
| Symbol |
GHS02 |
Signal Word | Warning | |
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Synthesis of alpha,alpha-dibromo esters as precursors of ynolates.
Chem. Pharm. Bull. 51(4) , 477-78, (2003) Aliphatic alpha,alpha-dibromo esters, precursors of ynolates, were synthesized via bromination of lithium alpha-bromo ester enolates with 1,2-dibromotetrafluoroethane in good yields. alpha-Trimethylsilyl-alpha,alpha-dibromo esters were synthesized via radical... |
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External chiral ligand-mediated enantioselective Peterson reaction of alpha-trimethylsilanylacetate with substituted cyclohexanones.
Org. Lett. 4 , 4329, (2002) [reaction: see text] The asymmetric Peterson reaction of an alpha-trimethylsilanylacetate with 4-substituted and 3,5-disubstituted cyclohexanones was mediated by an external chiral tridentate ligand to give the corresponding olefins with an axial chirality in... |
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Synth. Commun. 19 , 2441, (1989)
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J. Chem. Soc. Perkin Trans. I , 3217, (1988)
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Synthesis and Cleavage of Ethyl Trimethylsilylacetate1, 2. Gold JR, et al.
J. Am. Chem. Soc. 70(9) , 2874-76, (1948)
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New synthesis of. alpha.,. beta.-unsaturated carboxylic esters. Shimoji K, et al.
J. Am. Chem. Soc. 96(5) , 1620-21, (1974)
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P. Albaugh-Robertson, J.A.Katzenellenbogen
J. Org. Chem. 48 , 5288, (1983)
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T.V. RajanBabu
J. Org. Chem. 49 , 2083, (1984)
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I. Kuwajima et al.
Organic Synth. 61 , 122, (1983)
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