Tetrabutylammonium hydroxide

Tetrabutylammonium hydroxide Structure
Tetrabutylammonium hydroxide structure
Common Name Tetrabutylammonium hydroxide
CAS Number 2052-49-5 Molecular Weight 259.471
Density 0.995 Boiling Point 100 °C
Molecular Formula C16H37NO Melting Point 27-30 °C(lit.)
MSDS Chinese USA Flash Point 7°C
Symbol GHS05
GHS05
Signal Word Danger

High-turnover hypoiodite catalysis for asymmetric synthesis of tocopherols.

Science 345(6194) , 291-4, (2014)

The diverse biological activities of tocopherols and their analogs have inspired considerable interest in the development of routes for their efficient asymmetric synthesis. Here, we report that chiral ammonium hypoiodite salts catalyze highly chemo- and enan...

Tandem cyclization of α-cyano α-alkynyl aryl ketones induced by tert-butyl hydroperoxide and tetrabutylammonium iodide.

Org. Lett. 14(23) , 6024-7, (2012)

The radical cascade protocol of the α-cyano α-TMS/aryl-capped alkynyl aryl ketones promoted by tert-butyl hydroperoxide under catalysis with tetrabutylammonium iodide in refluxing benzene has been developed, leading to the construction of a variety of highly ...

1-Aza-15-Crown-5 Functionalized Graphene Oxide for 2D Graphene-Based Li⁺-ion Conductor.

Small 11 , 3451-7, (2015)

Attachment of Li(+) ion on graphene surface to realize Li(+)-ion conductor is a real challenge because of the weak interaction between the ions and the functional groups of graphene oxide; although, a large number of theoretical results are already available ...

Remarkably regioselective deacylation of cellulose esters using tetraalkylammonium salts of the strongly basic hydroxide ion.

Carbohydr. Polym. 111 , 25-32, (2014)

Tetraalkylammonium hydroxides have been found to mediate regioselective deacylation of cellulose esters. This deacylation surprisingly shows substantial selectivity for the removal of the acyl groups at O-2/3, affording cellulose-6-O-esters by a simple, effic...

Use of ion-pairing reagent for improving iodine speciation analysis in seaweed by pressure-driven capillary electrophoresis and ultraviolet detection.

J. Chromatogr. A. 1379 , 112-7, (2015)

This study achieved resolution improvement for iodine speciation in the presence of an ion-pairing reagent by a pressure-driven capillary electrophoresis (CE) system. Addition of 0.01mM tetrabutyl ammonium hydroxide (TBAH) as the ion-pairing reagent into the ...

Inhibition of Na(+)/K(+)-ATPase and cytotoxicity of a few selected gold(III) complexes.

J. Inorg. Biochem. 140 , 228-35, (2014)

Na(+)/K(+)-ATPase is in charge of maintaining the ionic and osmotic intracellular balance by using ATP as an energy source to drive excess Na(+) ions out of the cell in exchange for K(+) ions. We explored whether three representative cytotoxic gold(III) compo...

A New Hyaluronic Acid Derivative Obtained from Atom Transfer Radical Polymerization as a siRNA Vector for CD44 Receptor Tumor Targeting.

Macromol. Biosci. 15 , 1605-15, (2015)

Two derivatives of hyaluronic acid (HA) have been synthesized by atom transfer radical polymerization (ATRP), starting from an ethylenediamino HA derivative (HA-EDA) and by using diethylaminoethyl methacrylate (DEAEMA) as a monomer for polymerization. Both sa...

Nanomimics of host cell membranes block invasion and expose invasive malaria parasites.

ACS Nano 8(12) , 12560-71, (2014)

The fight against most infectious diseases, including malaria, is often hampered by the emergence of drug resistance and lack or limited efficacies of vaccines. Therefore, new drugs, vaccines, or other strategies to control these diseases are needed. Here, we...

Molecularly imprinted polymers for cleanup and selective extraction of curcuminoids in medicinal herbal extracts.

Anal. Bioanal. Chem 407(3) , 803-12, (2015)

This paper describes the synthesis of novel molecularly imprinted polymers (MIPs), prepared by a noncovalent imprinting approach, for cleanup and preconcentration of curcumin (CUR) and bisdemethoxycurcumin (BDMC) from medicinal herbal extracts and further ana...

Zwitterionic red fluorescent polymeric nanoparticles for cell imaging.

Macromol. Biosci. 14(10) , 1361-7, (2014)

Phospholipid monomer and aggregation-induced emission (AIE) dye-based dimers are incorporated via reversible addition-fragmentation transfer polymerization to afford cross-linked zwitterionic fluorescent copolymers. Such copolymers are prone to self-assembly ...