5-Bromo-2-chloropyrimidine
5-Bromo-2-chloropyrimidine structure
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Common Name | 5-Bromo-2-chloropyrimidine | ||
|---|---|---|---|---|
| CAS Number | 32779-36-5 | Molecular Weight | 193.43 | |
| Density | 1.9±0.1 g/cm3 | Boiling Point | 291.6±13.0 °C at 760 mmHg | |
| Molecular Formula | C4H2BrClN2 | Melting Point | 76-81 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 130.1±19.8 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Cross-coupling reactions of indium organometallics with 2,5-dihalopyrimidines: synthesis of hyrtinadine A.
Org. Lett. 10(17) , 3745-8, (2008) The palladium-catalyzed cross-coupling reaction of triorganoindium reagents (R3In) with 5-bromo-2-chloropyrimidine proceeds chemoselectively, in good yields, to give 5-substituted-2-chloropyrimidines or 2,5-disubstituted pyrimidines using 40 or 100 mol % of R... |
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Improved synthesis of 2,2'-bipyrimidine.
J. Org. Chem. 67(18) , 6550-2, (2002) A high-yield synthesis was developed for the preparation of 2,2'-bipyrimidine (1) using the Ullmann coupling of 2-iodopyrimidine. The new procedure was also used for the preparation of 4,4',6,6'-tetramethyl-2,2'-bipyrimidine (2) and 5,5'-dibromo-2,2'-bipyrimi... |
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