(Triphenylphosphoranylidene)acetonitrile
(Triphenylphosphoranylidene)acetonitrile structure
|
Common Name | (Triphenylphosphoranylidene)acetonitrile | ||
|---|---|---|---|---|
| CAS Number | 16640-68-9 | Molecular Weight | 301.322 | |
| Density | 1.2±0.1 g/cm3 | Boiling Point | 465.3±28.0 °C at 760 mmHg | |
| Molecular Formula | C20H16NP | Melting Point | 189-195ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 235.2±24.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
A highly regio- and stereoselective formation of bicyclo[4.2.0]oct-5-ene derivatives through thermal intramolecular [2 + 2] cycloaddition of allenes.
J. Org. Chem. 72 , 4378, (2007) Thermal [2 + 2] cycloaddition of allenes with an additional multiple bond is described. By simply heating the allenenes or allenynes having a three-atom tether in an appropriate solvent such as dioxane or DMF, the distal double bond of the allenic moiety regi... |
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