Diiron nonacarbonyl
Diiron nonacarbonyl structure
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Common Name | Diiron nonacarbonyl | ||
|---|---|---|---|---|
| CAS Number | 15321-51-4 | Molecular Weight | 363.78100 | |
| Density | 2.85 g/cm3 | Boiling Point | 209°C (rough estimate) | |
| Molecular Formula | C9Fe2O9 | Melting Point | 100ºC | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS02, GHS06 |
Signal Word | Danger | |
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Time-dependent density functional theory study of Fe2(CO)9 low-lying electronic excited states.
J. Phys. Chem. A 110(47) , 12900-7, (2006) The valence electronic excited states of Fe2(CO)9 have been studied using the time-dependent density functional theory (TDDFT). Both tribridged D3h and monobridged C2v structures have been considered, and the structure of selected low-lying singlet and triple... |
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Structure and bonding in binuclear metal carbonyls from the analysis of domain averaged Fermi holes. I. Fe2(CO)9 and Co2(CO)8.
J. Comput. Chem. 29(9) , 1387-98, (2008) The nature of the bonding in the above carbonyls was studied using the analysis of domain averaged Fermi holes (DAFH). The results straightforwardly confirm the conclusions of earlier theoretical studies in which the existence of direct metal-metal bond, anti... |
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Structure and energetics of Fe2(CO)8 singlet and triplet electronic states.
J. Phys. Chem. A 111(48) , 12152-62, (2007) The singlet and triplet state potential energy surfaces (PES) of Fe2(CO)8 are explored by means of density functional theory (DFT) techniques. The two PES have different global mimima: the dibriged C(2v) isomer for the singlet and the unbridged D(2d) isomer f... |
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Unusual reactions of [{micro-(phthalazine-N2:N3)}Fe2(micro-CO)(CO)6] with organolithium reagents. A novel coordination mode of 1,2-diazane diiron carbonyl compounds.
Dalton Trans. (4) , 603-8, (2006) [{Micro-(phthalazine-N2:N3)}Fe2(micro-CO)(CO)6](1) reacts with organolithium reagents, RLi (R = CH3, C6H5, p-CH3C6H4, p-CH3OC6H4, p-CF3C6H4, p-C6H5C6H4), followed by treatment with Me3SiCl to give the novel diiron carbonyl complexes with a saturated N-N six-m... |
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Simons, R.S. Tessier, C.A.
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