Ethyl benzimidate hydrochloride

Ethyl benzimidate hydrochloride Structure
Ethyl benzimidate hydrochloride structure
Common Name Ethyl benzimidate hydrochloride
CAS Number 5333-86-8 Molecular Weight 149.190
Density 1.0±0.1 g/cm3 Boiling Point 192.9±23.0 °C at 760 mmHg
Molecular Formula C9H12ClNO Melting Point 125ºC (dec.)
MSDS Chinese USA Flash Point 70.5±22.6 °C
Symbol GHS07
GHS07
Signal Word Warning

Efficient asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-alpha-methylcysteine using camphorsultam as a chiral auxiliary.

J. Org. Chem. 69(13) , 4551-4, (2004)

(1R)-(+)-2,10- and (1S)-(-)-2,10-camphorsultam were acylated with ethyl 2-phenylthiazoline 4-carboxylate to afford (+)- and (-)-2-phenylthiazolinylcamphorsultam, which were stereoselectively alkylated with MeI in the presence of n-BuLi. Alkylation of these ph...

The Synthesis of Substituted Penicillins and Simpler Structural Analogs. III. Phthalimido ß-Lactam-Thiazolidines Derived from Penicillamine. Sheehan JC, et al.

J. Am. Chem. Soc. 73(9) , 4373-4375, (1951)