4-Picoline

4-Picoline Structure
4-Picoline structure
Common Name 4-Picoline
CAS Number 108-89-4 Molecular Weight 93.127
Density 0.9±0.1 g/cm3 Boiling Point 144.2±9.0 °C at 760 mmHg
Molecular Formula C6H7N Melting Point 2.4 °C(lit.)
MSDS Chinese USA Flash Point 56.7±0.0 °C
Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger

cIEF for rapid pKa determination of small molecules: a proof of concept.

Eur. J. Pharm. Sci. 63 , 14-21, (2014)

A capillary isoelectric focusing (cIEF) method was developed for the determination of the ionization constants (pKa) of small molecules. Two approaches used to decrease the electroosmotic flow (EOF) were compared: (i) a hydroxypropylcellulose (HPC) coated cap...

Magnesium hydrides and the dearomatisation of pyridine and quinoline derivatives.

Dalton Trans. 40(46) , 12500-9, (2011)

Reactions of the β-diketiminato n-butyl magnesium complex, [HC{(Me)CN(2,6-(i)Pr(2)C(6)H(3))}(2)Mg(n)Bu], with a range of substituted pyridines and fused-ring quinolines in the presence of PhSiH(3) has been found to result in dearomatisation of the N-heterocyc...

Probing the nature of the Co(III) ion in corrins: comparison of reactions of aquacyanocobyrinic acid heptamethyl ester and aquacyano-stable yellow cobyrinic acid hexamethyl ester with neutral N-donor ligands.

Inorg. Chem. 52(2) , 1077-83, (2013)

Equilibrium constants (log K) for substitution of coordinated H(2)O in aquacyanocobyrinic acid heptamethyl ester (aquacyanocobester, ACCbs) and aquacyano-stable yellow cobyrinic acid hexamethyl ester (aquacyano-stable yellow cobester, ACSYCbs), in which oxida...