1,3-Dimethoxybenzene

1,3-Dimethoxybenzene Structure
1,3-Dimethoxybenzene structure
Common Name 1,3-Dimethoxybenzene
CAS Number 151-10-0 Molecular Weight 138.164
Density 1.0±0.1 g/cm3 Boiling Point 217.5±0.0 °C at 760 mmHg
Molecular Formula C8H10O2 Melting Point -52°C
MSDS Chinese USA Flash Point 87.8±0.0 °C

Rotamers of o- and m-dimethoxybenzenes studied by mass-analyzed threshold ionization spectroscopy and theoretical calculations.

J. Phys. Chem. A 114(42) , 11144-52, (2010)

We applied two-color resonant two-photon mass-analyzed threshold ionization (MATI) spectroscopy to investigate the molecular properties of the selected rotamers of o-dimethoxybenzene (ODMB) and m-dimethoxybenzene (MDMB). The present experimental results show ...

Stereoselective glycosylations using oxathiane spiroketal glycosyl donors.

Carbohydr. Res. 348 , 6-13, (2012)

Novel oxathiane spiroketal donors have been synthesised and activated via an umpolung S-arylation strategy using 1,3,5-trimethoxybenzene and 1,3-dimethoxybenzene. The comparative reactivity of the resulting 2,4,6-trimethoxyphenyl (TMP)- and 2,4-dimethoxypheny...

Solvation of dichlorocarbene: complexation with aryl ethers.

J. Phys. Chem. A 114(1) , 209-17, (2010)

Dichlorocarbene (CCl(2)), generated by laser flash photolysis of dichlorodiazirine, formed pi- and O-ylidic complexes with aromatic ethers such as anisole, 1,3-dimethoxybenzene, 1,3,5-trimethoxybenzene, dibenzofuran, and dibenzo-18-crown-6 and with the aromat...

Decrease in glucose oxidation in isolated brown fat cells from rats due to tropolone and dimethoxybenzene.

Gen. Pharmacol. 12(1) , 47-50, (1981)

1. 1. Glucose conversion to carbon dioxide in control and insulin treated brown fat cells is reduced in the presence of tropolone and dimethoxybenzene. 2. 2. The effects of ortho-, meta- and para-dimethoxybenzene are similar to each other; all are more potent...

C-terminal N-alkylated peptide amides resulting from the linker decomposition of the Rink amide resin: a new cleavage mixture prevents their formation.

J. Pept. Sci. 12(3) , 227-32, (2006)

Decomposition of the resin linkers during TFA cleavage of the peptides in the Fmoc strategy leads to alkylation of sensitive amino acids. The C-terminal amide alkylation, reported for the first time, is shown to be a major problem in peptide amides synthesize...

Optimization of the solid-phase microextraction method in the determination of Ixodes ricinus (L.) volatiles.

J. Sep. Sci. 29(2) , 236-41, (2006)

For the first time, headspace solid-phase microextraction coupled with GC-MS analysis was used to study volatile compounds emitted by the tick Ixodes ricinus (L.). Variables such as the type of SPME fibre, equilibration time and extraction time have been eval...

Short-step synthesis of a resveratrol derivative from commercially available 1,3-dimethoxybenzene and 4-vinylanisole.

Biosci. Biotechnol. Biochem. 73(11) , 2547-8, (2009)

An efficient synthesis of tri-O-methylated resveratrol is presented using an advanced Heck reaction promoted by Pd(dba)(2) in the presence of P(t-Bu)(3).

Formation of an unusual dimeric compound by lead tetraacetate oxidation of a corynanthe-type indole alkaloid, mitragynine.

Chem. Pharm. Bull. 50(7) , 960-3, (2002)

Lead tetraacetate oxidation of a Corynanthe-type indole alkaloid, mitragynine, produced mainly 7-acetoxyindolenine derivative (2) together with a dimeric compound (4) as a minor product. The novel structure having a bridge between the C-11' and C-7 positions ...